FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2913796611> ?p ?o ?g. }

• W2913796611 endingPage "35" @default.
• W2913796611 startingPage "22" @default.
• W2913796611 abstract "Background: Thermal decomposition of iron-bearing organometallic complex acetyl ferrocene, (C5H4COCH3)Fe(C5H5), leads to hematite (α-Fe2O3) nanoparticles. Presence of maliec anhydride, C4H2O3 as co-precursor during thermal decomposition modifies the size of the particles as well as the quantity of the reaction product significantly. Objective: Kinetic analysis of the solid-state thermal reaction of acetyl ferrocene in the presence of varying amount of co-precursor maliec anhydride under inert reaction atmosphere has been studied in order to understand the reaction mechanism involved behind the formation of hematite and the role of co-precursor in the reaction process. For this purpose, reaction kinetic analysis of three mixtures of acetyl ferrocene and maliec anhydride has been carried out. Methods: Thermogravimetry under non-isothermal protocol with multiple heating rates has been employed. The data are analyzed using model-free iso-conversional kinetic techniques to estimate the activation energy of reaction and reaction rate. The most-probable reaction mechanism has been identified by master plot method. The kinetic triplets (activation energy, reaction rate, most probable reaction mechanism function) have been employed to estimate the thermodynamic triplets (ΔS, ΔH and ΔG). Observations: Acetyl Ferrocene (AFc) undergoes thermal decomposition in a four-step process leaving certain residual mass whereas maliec anhydride (MA) undergoes complete mass loss owing to melting followed by evaporation. In contrast, the (AFc1-x-MAx) mixtures undergo thermal decomposition through a two-step process, and the decompositions are completed at much lower temperatures than that in AFc. The estimated activation energy and reaction rate values are found strongly dependent on the extent of conversion as well as on the extent of mixing. Introduction of MA in the solid reaction atmosphere of AFc in one hand reduces the activation energy required by AFc to undergo thermal decomposition and the reaction rate, while on the other hand varies the nature of reaction mechanism involved. Results: The range of reaction rate values estimated for the mixtures indicate that the activated complexes during Step-I of thermal decomposition may be treated as ‘loose’ complex whereas ‘tight’ complex for the Step-II. From the estimated entropy values, thermal process of (AFc1-x-MAx) mixture for Steps I and II may be interpreted as ‘‘slow’’ stage. Conclusion: Variation of Gibb’s free energy with the fraction of maliec anhydride in the mixtures for Step-I and II indicate that the thermal processes of changing the corresponding activated complexes are non-spontaneous at room temperature." @default.
• W2913796611 created "2019-02-21" @default.
• W2913796611 creator A5009365544 @default.
• W2913796611 creator A5075389923 @default.
• W2913796611 date "2019-06-03" @default.
• W2913796611 modified "2023-09-27" @default.
• W2913796611 title "Effect of Co-precursor Maliec Anhydride on the Thermal Decomposition of Acetyl Ferrocene: A Reaction Kinetic Analysis" @default.
• W2913796611 cites W1753230822 @default.
• W2913796611 cites W1964740351 @default.
• W2913796611 cites W1973887862 @default.
• W2913796611 cites W1986925386 @default.
• W2913796611 cites W1997844747 @default.
• W2913796611 cites W2008854263 @default.
• W2913796611 cites W2011806614 @default.
• W2913796611 cites W2017125573 @default.
• W2913796611 cites W2023142109 @default.
• W2913796611 cites W2041826578 @default.
• W2913796611 cites W2044194865 @default.
• W2913796611 cites W2045206840 @default.
• W2913796611 cites W2053490506 @default.
• W2913796611 cites W2054179844 @default.
• W2913796611 cites W2063431185 @default.
• W2913796611 cites W2069321098 @default.
• W2913796611 cites W2118445097 @default.
• W2913796611 cites W2143903688 @default.
• W2913796611 cites W2725870546 @default.
• W2913796611 cites W2766627065 @default.
• W2913796611 cites W2963376123 @default.
• W2913796611 cites W4255458428 @default.
• W2913796611 cites W755084011 @default.
• W2913796611 doi "https://doi.org/10.2174/1877946809666190201142153" @default.
• W2913796611 hasPublicationYear "2019" @default.
• W2913796611 type Work @default.
• W2913796611 sameAs 2913796611 @default.
• W2913796611 citedByCount "1" @default.
• W2913796611 countsByYear W29137966112023 @default.
• W2913796611 crossrefType "journal-article" @default.
• W2913796611 hasAuthorship W2913796611A5009365544 @default.
• W2913796611 hasAuthorship W2913796611A5075389923 @default.
• W2913796611 hasConcept C121332964 @default.
• W2913796611 hasConcept C124681953 @default.
• W2913796611 hasConcept C133347239 @default.
• W2913796611 hasConcept C135502975 @default.
• W2913796611 hasConcept C147789679 @default.
• W2913796611 hasConcept C148898269 @default.
• W2913796611 hasConcept C160434732 @default.
• W2913796611 hasConcept C161790260 @default.
• W2913796611 hasConcept C175113610 @default.
• W2913796611 hasConcept C17525397 @default.
• W2913796611 hasConcept C178790620 @default.
• W2913796611 hasConcept C179104552 @default.
• W2913796611 hasConcept C185592680 @default.
• W2913796611 hasConcept C190463131 @default.
• W2913796611 hasConcept C19418292 @default.
• W2913796611 hasConcept C2777237805 @default.
• W2913796611 hasConcept C39588626 @default.
• W2913796611 hasConcept C52859227 @default.
• W2913796611 hasConcept C55766333 @default.
• W2913796611 hasConcept C62520636 @default.
• W2913796611 hasConcept C65024703 @default.
• W2913796611 hasConcept C93391505 @default.
• W2913796611 hasConcept C95121573 @default.
• W2913796611 hasConcept C97355855 @default.
• W2913796611 hasConceptScore W2913796611C121332964 @default.
• W2913796611 hasConceptScore W2913796611C124681953 @default.
• W2913796611 hasConceptScore W2913796611C133347239 @default.
• W2913796611 hasConceptScore W2913796611C135502975 @default.
• W2913796611 hasConceptScore W2913796611C147789679 @default.
• W2913796611 hasConceptScore W2913796611C148898269 @default.
• W2913796611 hasConceptScore W2913796611C160434732 @default.
• W2913796611 hasConceptScore W2913796611C161790260 @default.
• W2913796611 hasConceptScore W2913796611C175113610 @default.
• W2913796611 hasConceptScore W2913796611C17525397 @default.
• W2913796611 hasConceptScore W2913796611C178790620 @default.
• W2913796611 hasConceptScore W2913796611C179104552 @default.
• W2913796611 hasConceptScore W2913796611C185592680 @default.
• W2913796611 hasConceptScore W2913796611C190463131 @default.
• W2913796611 hasConceptScore W2913796611C19418292 @default.
• W2913796611 hasConceptScore W2913796611C2777237805 @default.
• W2913796611 hasConceptScore W2913796611C39588626 @default.
• W2913796611 hasConceptScore W2913796611C52859227 @default.
• W2913796611 hasConceptScore W2913796611C55766333 @default.
• W2913796611 hasConceptScore W2913796611C62520636 @default.
• W2913796611 hasConceptScore W2913796611C65024703 @default.
• W2913796611 hasConceptScore W2913796611C93391505 @default.
• W2913796611 hasConceptScore W2913796611C95121573 @default.
• W2913796611 hasConceptScore W2913796611C97355855 @default.
• W2913796611 hasFunder F4320326272 @default.
• W2913796611 hasIssue "1" @default.
• W2913796611 hasLocation W29137966111 @default.
• W2913796611 hasOpenAccess W2913796611 @default.
• W2913796611 hasPrimaryLocation W29137966111 @default.
• W2913796611 hasRelatedWork W1792111348 @default.
• W2913796611 hasRelatedWork W1980106806 @default.
• W2913796611 hasRelatedWork W2045647275 @default.
• W2913796611 hasRelatedWork W2073224268 @default.
• W2913796611 hasRelatedWork W2170864052 @default.
• W2913796611 hasRelatedWork W2354653259 @default.

• next