Matches in SemOpenAlex for { <https://semopenalex.org/work/W2913962717> ?p ?o ?g. }
- W2913962717 endingPage "272" @default.
- W2913962717 startingPage "261" @default.
- W2913962717 abstract "Cyclophanediene (CPD)-dihydropyrene (DHP) is a negative T-type photochrome pair having a thermodynamically stable colored form, i.e., DHP. Interconversion between cyclophanediene and dihydropyrene is associated with significant changes in dipole moment, absorption wavelength and polarizability, which can impart substantial linear and nonlinear optical response. In this study, phototunable linear and nonlinear optical response of cyclophanediene-dihdyropyrene photoswitches is described. Cyclophanedienes and dihydropyrenes are functionalized at the internal position for maximum changes in volume and polarizability. The UV–Vis spectra are calculated at ɷB97XD, which was validated through a benchmark approach. An excellent correlation is observed between theoretical and experimental absorption spectra. Several CPD-DHP pairs have been recognized for clean interconversion in UV–Vis light without formation of a photostationary state. Nonlinear optical response of dihydropyrenes is remarkably higher than that of cyclophanedienes. In general, the calculated hyperpolarizability values of dihydropyrenes are about two to three orders of magnitude higher than those for cyclophanedienes. The trends in calculated hyperpolarizabilities are rationalized through two level method. The high nonlinear optical response of dihydropyrenes stems from low excitation energies. The remarkable difference in hyperpolarizabilities of these isomeric forms paves path for the design of phototunable nonlinear optical materials." @default.
- W2913962717 created "2019-02-21" @default.
- W2913962717 creator A5006327973 @default.
- W2913962717 creator A5020641848 @default.
- W2913962717 creator A5030888648 @default.
- W2913962717 creator A5037024089 @default.
- W2913962717 creator A5040582281 @default.
- W2913962717 creator A5045033456 @default.
- W2913962717 creator A5071014140 @default.
- W2913962717 creator A5078893914 @default.
- W2913962717 date "2019-05-01" @default.
- W2913962717 modified "2023-09-27" @default.
- W2913962717 title "Photo-tunable linear and nonlinear optical response of cyclophanediene-dihydropyrene photoswitches" @default.
- W2913962717 cites W1969777621 @default.
- W2913962717 cites W1970952020 @default.
- W2913962717 cites W1974864700 @default.
- W2913962717 cites W1975879685 @default.
- W2913962717 cites W1977935845 @default.
- W2913962717 cites W1980807635 @default.
- W2913962717 cites W1982355062 @default.
- W2913962717 cites W1988946740 @default.
- W2913962717 cites W1994113474 @default.
- W2913962717 cites W1995433329 @default.
- W2913962717 cites W2002365353 @default.
- W2913962717 cites W2003566444 @default.
- W2913962717 cites W2003993631 @default.
- W2913962717 cites W2004349465 @default.
- W2913962717 cites W2005508670 @default.
- W2913962717 cites W2007562606 @default.
- W2913962717 cites W2008042597 @default.
- W2913962717 cites W2008423326 @default.
- W2913962717 cites W2008920194 @default.
- W2913962717 cites W2011079470 @default.
- W2913962717 cites W2011184332 @default.
- W2913962717 cites W2011204155 @default.
- W2913962717 cites W2014333836 @default.
- W2913962717 cites W2020250273 @default.
- W2913962717 cites W2021320781 @default.
- W2913962717 cites W2023016621 @default.
- W2913962717 cites W2024204326 @default.
- W2913962717 cites W2027786122 @default.
- W2913962717 cites W2028751304 @default.
- W2913962717 cites W2035887397 @default.
- W2913962717 cites W2045663488 @default.
- W2913962717 cites W2048204582 @default.
- W2913962717 cites W2054428590 @default.
- W2913962717 cites W2054562486 @default.
- W2913962717 cites W2054704030 @default.
- W2913962717 cites W2056873826 @default.
- W2913962717 cites W2058363175 @default.
- W2913962717 cites W2062764046 @default.
- W2913962717 cites W2062852634 @default.
- W2913962717 cites W2064009442 @default.
- W2913962717 cites W2075582546 @default.
- W2913962717 cites W2076247922 @default.
- W2913962717 cites W2082315169 @default.
- W2913962717 cites W2084393997 @default.
- W2913962717 cites W2086132254 @default.
- W2913962717 cites W2087623884 @default.
- W2913962717 cites W2090329067 @default.
- W2913962717 cites W2105564141 @default.
- W2913962717 cites W2108895817 @default.
- W2913962717 cites W2112850441 @default.
- W2913962717 cites W2115427760 @default.
- W2913962717 cites W2120120361 @default.
- W2913962717 cites W2143981217 @default.
- W2913962717 cites W2144240724 @default.
- W2913962717 cites W2150195378 @default.
- W2913962717 cites W2150697053 @default.
- W2913962717 cites W2169639756 @default.
- W2913962717 cites W2186035301 @default.
- W2913962717 cites W2192780982 @default.
- W2913962717 cites W2314639793 @default.
- W2913962717 cites W2316937443 @default.
- W2913962717 cites W2319774976 @default.
- W2913962717 cites W2325882572 @default.
- W2913962717 cites W2326379355 @default.
- W2913962717 cites W2333155750 @default.
- W2913962717 cites W2335519179 @default.
- W2913962717 cites W2435573151 @default.
- W2913962717 cites W2521192183 @default.
- W2913962717 cites W2522732241 @default.
- W2913962717 cites W2604220762 @default.
- W2913962717 cites W2739026302 @default.
- W2913962717 cites W2754665299 @default.
- W2913962717 cites W2758161021 @default.
- W2913962717 cites W2766255287 @default.
- W2913962717 cites W2789948962 @default.
- W2913962717 cites W2790968295 @default.
- W2913962717 cites W2810807719 @default.
- W2913962717 cites W2855117801 @default.
- W2913962717 cites W2886684213 @default.
- W2913962717 cites W2887148021 @default.
- W2913962717 cites W2888289210 @default.
- W2913962717 cites W2900879334 @default.
- W2913962717 cites W2906660530 @default.
- W2913962717 cites W342505597 @default.
- W2913962717 cites W760052855 @default.