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• W2914215149 abstract "Hemisquaramide tweezers, a new family of H-bond donor organocatalysts, are reported. The catalysts could be synthesized within two steps. Among them, H8-binaphthyl-linked hemisquaramide 7 markedly accelerated the synthesis of cyclic carbonates from epoxides and CO2. The reactions proceeded well under mild and solvent-free conditions. Kinetic resolution was also achieved at −20 °C (s = 3.0). The adjustable bite angle and orientation of the two NH groups of the catalysts are important for the high activity." @default.
• W2914215149 created "2019-02-21" @default.
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• W2914215149 date "2019-02-14" @default.
• W2914215149 modified "2023-10-15" @default.
• W2914215149 title "Hemisquaramide Tweezers as Organocatalysts: Synthesis of Cyclic Carbonates from Epoxides and CO₂" @default.
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• W2914215149 doi "https://doi.org/10.1021/acs.orglett.9b00117" @default.
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