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- W2914220544 abstract "A tandem synthetic route to a diverse array of cyclic compounds has been developed from Friedel–Crafts acylation of alkynes followed by the microwave irradiation of β-chlorovinyl ketone intermediates. The stereoisomeric β-chlorovinyl ketone intermediates smoothly underwent a thermal α-vinyl enolization and ring expansion to vinyl and carbocyclic furans as well as cyclopetene derivatives in good to excellent yields without the need for any catalysts." @default.
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- W2914220544 date "2019-01-23" @default.
- W2914220544 modified "2023-10-14" @default.
- W2914220544 title "Tandem Transformations via Friedel–Crafts Acylation Followed by a Ring-Expansion, Ring-Opening, and Cycloisomerization Sequence" @default.
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- W2914220544 doi "https://doi.org/10.1021/acs.orglett.8b03881" @default.
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