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- W2914232334 abstract "The new transition metal oxo‐thiostannate {[Ni(cyclen)] 6 [Sn 6 S 12 O 2 (OH) 6 ]} · 2(ClO 4 ) · 19H 2 O ( 1 ) was prepared under hydrothermal conditions using Na 4 SnS 4 · 14H 2 O and [Ni(cyclen)](ClO 4 ) 2 as reactants. In the crystal structure the rare [Sn 6 S 12 O 2 (OH) 6 ] 10– anion is observed, which is composed of SnS 2 O(OH) 3 and SnS 4 O 2 octahedra, and SnS 4 tetrahedra sharing edges and corners. The anion is expanded by six Ni 2+ centered complexes via Ni–S and Ni–OH bonds. The photocatalytic properties for the visible light driven hydrogen evolution reaction shows that 26.6 mmol · g –1 H 2 were evolved after 3 h." @default.
- W2914232334 created "2019-02-21" @default.
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- W2914232334 date "2019-01-23" @default.
- W2914232334 modified "2023-10-14" @default.
- W2914232334 title "New Transition Metal Oxo-Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties" @default.
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- W2914232334 doi "https://doi.org/10.1002/zaac.201800475" @default.
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