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• W2914284102 abstract "A pair of structurally precise analogues of molybdenum and rhenium complexes, [Et4N]/K2[MoO(prdt)2] and K[ReO(prdt)2] (prdt = pyrazine-2,3-dithiolene), were synthesized. These complexes serve as structural models for the active sites of bacterial molybdenum cofactor containing enzymes. They were comprehensively characterized and investigated by NMR, computationally supported IR and resonance Raman spectroscopy, cyclic voltammetry, mass spectrometry, elemental analysis and single-crystal X-ray diffraction. All compiled data are discussed in the context of comparing chemical and electronic structures and consequences thereof. This study constitutes the first investigation of a potential alternative Moco model system bearing rhenium as the central metal in an identical coordination environment to its molybdenum analogue. Structural evaluation revealed a slightly stronger M[double bond, length as m-dash]O bond in the rhenium complex in accordance with spectroscopic results, i.e. observed bond strengths. Thermodynamic parameters for the redox processes MoIV ↔ MoV and ReIV ↔ ReV were obtained by temperature dependent cyclic voltammetry. In contrast to molybdenum, rhenium loses entropy upon reduction and its redox potential is more temperature sensitive, indicating more significant differences than the respective diagonal relationship between the two metals in the periodic table might suggest and questioning rhenium's suitability as a functional artificial active site metal." @default.
• W2914284102 created "2019-02-21" @default.
• W2914284102 creator A5004242652 @default.
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• W2914284102 date "2019-01-01" @default.
• W2914284102 modified "2023-10-18" @default.
• W2914284102 title "Comparison of molybdenum and rhenium oxo bis-pyrazine-dithiolene complexes – in search of an alternative metal centre for molybdenum cofactor models" @default.
• W2914284102 cites W1967019492 @default.
• W2914284102 cites W1969078948 @default.
• W2914284102 cites W1970321021 @default.
• W2914284102 cites W1977025440 @default.
• W2914284102 cites W1980605942 @default.
• W2914284102 cites W1982519908 @default.
• W2914284102 cites W1985265491 @default.
• W2914284102 cites W1988091937 @default.
• W2914284102 cites W1988174151 @default.
• W2914284102 cites W1990170643 @default.
• W2914284102 cites W1990185494 @default.
• W2914284102 cites W1995330033 @default.
• W2914284102 cites W1997417815 @default.
• W2914284102 cites W1999711169 @default.
• W2914284102 cites W2002135348 @default.
• W2914284102 cites W2002473282 @default.
• W2914284102 cites W2004317657 @default.
• W2914284102 cites W2005393082 @default.
• W2914284102 cites W2006199697 @default.
• W2914284102 cites W2006243394 @default.
• W2914284102 cites W2007262355 @default.
• W2914284102 cites W2014140141 @default.
• W2914284102 cites W2015723183 @default.
• W2914284102 cites W2016620123 @default.
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• W2914284102 cites W2019468221 @default.
• W2914284102 cites W2021903482 @default.
• W2914284102 cites W2022012139 @default.
• W2914284102 cites W2026622071 @default.
• W2914284102 cites W2028498874 @default.
• W2914284102 cites W2029292244 @default.
• W2914284102 cites W2030687437 @default.
• W2914284102 cites W2031662464 @default.
• W2914284102 cites W2035741021 @default.
• W2914284102 cites W2038643119 @default.
• W2914284102 cites W2039767485 @default.
• W2914284102 cites W2040621849 @default.
• W2914284102 cites W2045245826 @default.
• W2914284102 cites W2046738998 @default.
• W2914284102 cites W2052143203 @default.
• W2914284102 cites W2053502538 @default.
• W2914284102 cites W2059378328 @default.
• W2914284102 cites W2061409885 @default.
• W2914284102 cites W2063334178 @default.
• W2914284102 cites W2068237497 @default.
• W2914284102 cites W2071102536 @default.
• W2914284102 cites W2071126747 @default.
• W2914284102 cites W2073020904 @default.
• W2914284102 cites W2075727354 @default.
• W2914284102 cites W2076165785 @default.
• W2914284102 cites W2079667104 @default.
• W2914284102 cites W2085551612 @default.
• W2914284102 cites W2086957099 @default.
• W2914284102 cites W2094496163 @default.
• W2914284102 cites W2094620728 @default.
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• W2914284102 cites W2105249240 @default.
• W2914284102 cites W2121057595 @default.
• W2914284102 cites W2130118277 @default.
• W2914284102 cites W2131350133 @default.
• W2914284102 cites W2135261637 @default.
• W2914284102 cites W2135811286 @default.
• W2914284102 cites W2159276203 @default.
• W2914284102 cites W2164223026 @default.
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• W2914284102 cites W2335019122 @default.
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• W2914284102 doi "https://doi.org/10.1039/c8dt04237c" @default.
• W2914284102 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30720825" @default.
• W2914284102 hasPublicationYear "2019" @default.
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