Matches in SemOpenAlex for { <https://semopenalex.org/work/W2914342034> ?p ?o ?g. }
- W2914342034 endingPage "3534" @default.
- W2914342034 startingPage "3527" @default.
- W2914342034 abstract "Three zeolitic pentaborates (H2en)[B5O8(OH)] (1, en = ethylenediamine), (Hen)2[Al(B5O10)] (2), (H2en)[NH(CH3)2][Al(B5O10)] (3) were solvothermally obtained by employing ethanediamine molecules as structure-directing agents (SDAs). The nonmetal borate of 1 features a noncentrosymmetric two-dimensional layered structure. Through introducing Al atoms as the linkers and regulating the reaction conditions of 1, two three-dimensional zeolitic open-framework aluminoborates, noncentrosymmetric (NCS) of 2 and centrosymmetric (CS) of 3, were achieved. Both 2 and 3 exhibit [Al(B5O10)] n2 n- zeolitic frameworks based on the same fundamental building blocks (FBBs). However, the different arrangements between two FBBs result in 2 showing a NCS framework with dia topology, while 3 presents CS framework with cag topology. The flexibility of linkages modes of the FBBs as well as the unique structure-directing functions play crucial roles in the different formations. Powder second-harmonic generation (SHG) measurements revealed that acentric 1 and 2 possess nonlinear optical activity and 2 is type I phase-matchable with SHG responses of ∼1.0 time for KDP (KH2PO4). Infrared and UV-vis diffuse reflectance spectroscopy, along with electronic structure calculations, were also performed for the materials." @default.
- W2914342034 created "2019-02-21" @default.
- W2914342034 creator A5011677079 @default.
- W2914342034 creator A5014217295 @default.
- W2914342034 creator A5037983061 @default.
- W2914342034 creator A5065654425 @default.
- W2914342034 creator A5070889653 @default.
- W2914342034 creator A5081177283 @default.
- W2914342034 date "2019-02-13" @default.
- W2914342034 modified "2023-10-15" @default.
- W2914342034 title "Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties" @default.
- W2914342034 cites W1952857672 @default.
- W2914342034 cites W1963505948 @default.
- W2914342034 cites W1969360633 @default.
- W2914342034 cites W1981368803 @default.
- W2914342034 cites W1982715630 @default.
- W2914342034 cites W1995708970 @default.
- W2914342034 cites W2000457267 @default.
- W2914342034 cites W2041893040 @default.
- W2914342034 cites W2045739425 @default.
- W2914342034 cites W2050264054 @default.
- W2914342034 cites W2050455259 @default.
- W2914342034 cites W2056342491 @default.
- W2914342034 cites W2063595263 @default.
- W2914342034 cites W2081738670 @default.
- W2914342034 cites W2087598829 @default.
- W2914342034 cites W2088494215 @default.
- W2914342034 cites W2092597442 @default.
- W2914342034 cites W2100639907 @default.
- W2914342034 cites W2106557187 @default.
- W2914342034 cites W2107141326 @default.
- W2914342034 cites W2107362041 @default.
- W2914342034 cites W2109774408 @default.
- W2914342034 cites W2119071994 @default.
- W2914342034 cites W2119321886 @default.
- W2914342034 cites W2120744473 @default.
- W2914342034 cites W2129559651 @default.
- W2914342034 cites W2130220047 @default.
- W2914342034 cites W2144097670 @default.
- W2914342034 cites W2159752439 @default.
- W2914342034 cites W2160104537 @default.
- W2914342034 cites W2166689829 @default.
- W2914342034 cites W2179728555 @default.
- W2914342034 cites W2184763987 @default.
- W2914342034 cites W2214641139 @default.
- W2914342034 cites W2231240753 @default.
- W2914342034 cites W2280549451 @default.
- W2914342034 cites W2283575573 @default.
- W2914342034 cites W2345439730 @default.
- W2914342034 cites W2464117348 @default.
- W2914342034 cites W2466693582 @default.
- W2914342034 cites W2531207561 @default.
- W2914342034 cites W2558935017 @default.
- W2914342034 cites W2562759326 @default.
- W2914342034 cites W2584364583 @default.
- W2914342034 cites W2588847771 @default.
- W2914342034 cites W2592339122 @default.
- W2914342034 cites W2608853786 @default.
- W2914342034 cites W2615133100 @default.
- W2914342034 cites W2738234176 @default.
- W2914342034 cites W2739026302 @default.
- W2914342034 cites W2767571272 @default.
- W2914342034 cites W2770196690 @default.
- W2914342034 cites W2784498212 @default.
- W2914342034 cites W2790968295 @default.
- W2914342034 cites W2791582335 @default.
- W2914342034 cites W2792923754 @default.
- W2914342034 cites W2800849345 @default.
- W2914342034 cites W2804353867 @default.
- W2914342034 cites W2885861415 @default.
- W2914342034 cites W2886137649 @default.
- W2914342034 cites W2887148021 @default.
- W2914342034 cites W2888492095 @default.
- W2914342034 cites W2888704582 @default.
- W2914342034 cites W2889604433 @default.
- W2914342034 cites W2898040668 @default.
- W2914342034 cites W2949482283 @default.
- W2914342034 cites W2949942113 @default.
- W2914342034 cites W2950399362 @default.
- W2914342034 cites W2951023404 @default.
- W2914342034 doi "https://doi.org/10.1021/acs.inorgchem.9b00101" @default.
- W2914342034 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30758951" @default.
- W2914342034 hasPublicationYear "2019" @default.
- W2914342034 type Work @default.
- W2914342034 sameAs 2914342034 @default.
- W2914342034 citedByCount "20" @default.
- W2914342034 countsByYear W29143420342019 @default.
- W2914342034 countsByYear W29143420342020 @default.
- W2914342034 countsByYear W29143420342021 @default.
- W2914342034 countsByYear W29143420342022 @default.
- W2914342034 countsByYear W29143420342023 @default.
- W2914342034 crossrefType "journal-article" @default.
- W2914342034 hasAuthorship W2914342034A5011677079 @default.
- W2914342034 hasAuthorship W2914342034A5014217295 @default.
- W2914342034 hasAuthorship W2914342034A5037983061 @default.
- W2914342034 hasAuthorship W2914342034A5065654425 @default.
- W2914342034 hasAuthorship W2914342034A5070889653 @default.
- W2914342034 hasAuthorship W2914342034A5081177283 @default.