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- W2914351193 abstract "Three molecular engineered [Ir(N^C)2(CF3pic)] complexes, where N^C are Fppy = 2-(2,4-difluorophenyl)pyridine, ppy = 2-phenylpyridine or Meppy = 2-(p-tolyl)pyridine, and CF3pic = 3-(trifluoromethyl)pyridine-2-carboxylate, are reported to elucidate their photophysical characteristics and emission profiles to emphasize rigidochromism. Their emission in fluid media is ascribed to a lowest-lying 3MLCT (metal-to-ligand charge transfer) excited state with emission quantum yields (ϕ) at room temperature of 0.13 for [Ir(Fppy)2(CF3pic)] and ϕ < 0.01 for other compounds. In poly(methyl methacrylate) (PMMA) and at 77 K, a medium effect is observed through prominent spectral changes assigned to destabilization of the 3MLCT state and emission originated from the 3LC (ligand center) state. Emission energies in different media are rationalized through energy diagrams and rigidity-dependence of the emitted color is thoroughly depicted through CIE coordinates." @default.
- W2914351193 created "2019-02-21" @default.
- W2914351193 creator A5012154406 @default.
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- W2914351193 creator A5086124381 @default.
- W2914351193 date "2019-05-01" @default.
- W2914351193 modified "2023-09-24" @default.
- W2914351193 title "Unraveling the luminescence of new heteroleptic Ir(III) cyclometalated series" @default.
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- W2914351193 doi "https://doi.org/10.1016/j.poly.2019.01.058" @default.
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