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- W2914462044 abstract "Emerging power batteries with both high volumetric energy density and fast charge/discharge kinetics are required for electric vehicles. The rapid ion/electron transport of mesostructured electrodes enables a high electrochemical activity in secondary batteries. However, the typical low fraction of active materials leads to a low volumetric energy density. Herein, we report a novel biomimetic bee pupa infilled honeycomb-structured 3D mesoporous cathode. We found previously the maximum active material filing fraction of an opal template before pinch-off was about 25%, whereas it could be increased to ∼90% with the bee pupa-infilled honeycomb-like architecture. Importantly, even with a high infilling fraction, fast Li+/e- transport kinetics and robust mechanical property were achievable. As the demonstration, a bee pupa infilled honeycomb-shaped Li2MnSiO4/C cathode was constructed, which delivered a high volumetric energy density of 2443 W h L-1. The presented biomimetic bee pupa infilled honeycomb configuration is applicable for a broad set of both cathodes and anodes in high energy density batteries." @default.
- W2914462044 created "2019-02-21" @default.
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- W2914462044 date "2019-01-01" @default.
- W2914462044 modified "2023-10-18" @default.
- W2914462044 title "A bee pupa-infilled honeycomb structure-inspired Li<sub>2</sub>MnSiO<sub>4</sub> cathode for high volumetric energy density secondary batteries" @default.
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- W2914462044 doi "https://doi.org/10.1039/c9cc00729f" @default.
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- W2914462044 hasPublicationYear "2019" @default.
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