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- W2914498426 abstract "A rhodium-catalyzed tandem reaction of alkynyl cyclobutanols with salicylaldehydes has been developed. The reaction offers a new and atom-economical approach for the selective preparation of multisubstituted 2-(2-oxo-2-phenylethyl)cyclopentanone in high yields under mild reaction conditions with tolerance of a broad range of substituted alkynyl cyclobutanols and salicylaldehyes. The isolation of intermediate suggests that the reaction proceeds through a sequential process of intermolecular hydroacylation and semipinacol rearrangement." @default.
- W2914498426 created "2019-02-21" @default.
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- W2914498426 date "2019-02-12" @default.
- W2914498426 modified "2023-10-11" @default.
- W2914498426 title "Synthesis of 2-(2-Oxo-2-phenylethyl)cyclopentanone by Rhodium-Catalyzed Tandem Alkynyl Cyclobutanols Hydroacylation and Semipinacol Rearrangement" @default.
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- W2914498426 doi "https://doi.org/10.1021/acs.orglett.8b03973" @default.
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