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- W2914510245 abstract "In this present study, zinc chloride-1-ethyl-3-methylimidazolium chloride (EMIC) was used to form a room temperature melt. Although these melts are being examined for electrochemical applications, little conductivity data appears in the literature. The sequence of conductivities for the different component melts is ZnCl2-EMIC > ZnCl2-EMIC-CoCl2 > ZnCl2-EMIC-DyCl3 > ZnCl2-EMIC-CoCl2-DyCl3. The results may be explained in terms of the viscosity increase and complex formation when the cobalt chloride or dysprosium chloride is added into the acidic ZnCl2-EMIC melt. The electrochemistry of cobalt(II) and/or dysprosium chloride in acidic ZnCl2-EMIC melts at different temperature has been investigated by cyclic voltammetry. The results reveal the reduction of Dy(III) to Dy(II) or Dy(III) to Dy may have occurred, and the electrodeposition of Co-Dy or Zn-Co-Dy alloys was not formed from the melt at 80°C. Nevertheless, the cathodic reduction of Co2+/Dy3+ species will occur more readily at 110°C and 120°C than at 100°C." @default.
- W2914510245 created "2019-02-21" @default.
- W2914510245 creator A5003977680 @default.
- W2914510245 date "2002-01-01" @default.
- W2914510245 modified "2023-09-24" @default.
- W2914510245 title "Conductivity and Electrochemistry of Cobalt (II) and Dysprosium Chloride in Zinc Chloride-1-Ethyl-3-Methyl-Imidazolium Chloride Room-Temperature Molten Salt" @default.
- W2914510245 doi "https://doi.org/10.1149/200219.0690pv" @default.
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