FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2914598286> ?p ?o ?g. }

• W2914598286 endingPage "7183" @default.
• W2914598286 startingPage "7174" @default.
• W2914598286 abstract "Understanding self-assembly behavior and resulting morphologies in block co-polymer films is an essential aspect of chemistry and materials science. Although the self-assembly of amorphous coil-coil block co-polymers is relatively well understood, that of semicrystalline block co-polymers where each block has distinct crystallization properties remains unclear. Here, we report a detailed study to elucidate the rich self-assembly behavior of conjugated thiophene-selenophene (P3AT- b-P3AS) block co-polymers. Using a combination of microscopy and synchrotron-based X-ray techniques, we show that three different film morphologies, denoted as lamellae, co-crystallized fibers, and patchy fibers, arise from the self-assembly of these block co-polymers over a relatively narrow range of overall degrees of polymerization (30 < N < 90). Crystallization-driven phase separation occurs at a very low N (<35), and lamellar films are formed. Conversely, at medium N (50-60) and high N (>80), the thiophene and selenophene blocks co-crystallize into nanofibers, where medium N leads to much more mixing than high N. The overall tendency for phase separation in these systems follows rather different trends than phase separation in amorphous polymers in that we observe the greatest degree of phase separation at the lowest N. Finally, we demonstrate how each morphology influences transport properties in organic thin-film transistors comprised of these conjugated polymers." @default.
• W2914598286 created "2019-02-21" @default.
• W2914598286 creator A5002529154 @default.
• W2914598286 creator A5011907765 @default.
• W2914598286 creator A5019302267 @default.
• W2914598286 creator A5025685909 @default.
• W2914598286 creator A5035017369 @default.
• W2914598286 creator A5060010515 @default.
• W2914598286 creator A5062017340 @default.
• W2914598286 creator A5066103491 @default.
• W2914598286 creator A5085630057 @default.
• W2914598286 date "2019-02-05" @default.
• W2914598286 modified "2023-10-16" @default.
• W2914598286 title "Poly(3-alkylthiophene)-<i>block</i>-poly(3-alkylselenophene)s: Conjugated Diblock Co-polymers with Atypical Self-Assembly Behavior" @default.
• W2914598286 cites W1965263500 @default.
• W2914598286 cites W1972683827 @default.
• W2914598286 cites W1976915466 @default.
• W2914598286 cites W1978140203 @default.
• W2914598286 cites W1982271883 @default.
• W2914598286 cites W1986073769 @default.
• W2914598286 cites W1988462300 @default.
• W2914598286 cites W1991395369 @default.
• W2914598286 cites W1992342771 @default.
• W2914598286 cites W1993352420 @default.
• W2914598286 cites W1994955082 @default.
• W2914598286 cites W1996397759 @default.
• W2914598286 cites W1997304772 @default.
• W2914598286 cites W1997947072 @default.
• W2914598286 cites W1999252869 @default.
• W2914598286 cites W2000512481 @default.
• W2914598286 cites W2009257878 @default.
• W2914598286 cites W2016452144 @default.
• W2914598286 cites W2016943360 @default.
• W2914598286 cites W2028951168 @default.
• W2914598286 cites W2034501059 @default.
• W2914598286 cites W2037241499 @default.
• W2914598286 cites W2038734585 @default.
• W2914598286 cites W2043483209 @default.
• W2914598286 cites W2043542701 @default.
• W2914598286 cites W2045612967 @default.
• W2914598286 cites W2058631786 @default.
• W2914598286 cites W2073402040 @default.
• W2914598286 cites W2075370047 @default.
• W2914598286 cites W2087513315 @default.
• W2914598286 cites W2090708418 @default.
• W2914598286 cites W2094396950 @default.
• W2914598286 cites W2101638216 @default.
• W2914598286 cites W2111258618 @default.
• W2914598286 cites W2116650273 @default.
• W2914598286 cites W2117669312 @default.
• W2914598286 cites W2137666255 @default.
• W2914598286 cites W2140088505 @default.
• W2914598286 cites W2142209863 @default.
• W2914598286 cites W2142325960 @default.
• W2914598286 cites W2148847401 @default.
• W2914598286 cites W2150621481 @default.
• W2914598286 cites W2152984864 @default.
• W2914598286 cites W2161289040 @default.
• W2914598286 cites W2163611288 @default.
• W2914598286 cites W2172949807 @default.
• W2914598286 cites W2314876455 @default.
• W2914598286 cites W2315532214 @default.
• W2914598286 cites W2318559630 @default.
• W2914598286 cites W2318709506 @default.
• W2914598286 cites W2320103394 @default.
• W2914598286 cites W2320800511 @default.
• W2914598286 cites W2329657133 @default.
• W2914598286 cites W2332047784 @default.
• W2914598286 cites W2561515125 @default.
• W2914598286 cites W2588093986 @default.
• W2914598286 cites W2801121244 @default.
• W2914598286 cites W95426343 @default.
• W2914598286 doi "https://doi.org/10.1021/acsami.8b18795" @default.
• W2914598286 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30720263" @default.
• W2914598286 hasPublicationYear "2019" @default.
• W2914598286 type Work @default.
• W2914598286 sameAs 2914598286 @default.
• W2914598286 citedByCount "24" @default.
• W2914598286 countsByYear W29145982862019 @default.
• W2914598286 countsByYear W29145982862020 @default.
• W2914598286 countsByYear W29145982862021 @default.
• W2914598286 countsByYear W29145982862022 @default.
• W2914598286 countsByYear W29145982862023 @default.
• W2914598286 crossrefType "journal-article" @default.
• W2914598286 hasAuthorship W2914598286A5002529154 @default.
• W2914598286 hasAuthorship W2914598286A5011907765 @default.
• W2914598286 hasAuthorship W2914598286A5019302267 @default.
• W2914598286 hasAuthorship W2914598286A5025685909 @default.
• W2914598286 hasAuthorship W2914598286A5035017369 @default.
• W2914598286 hasAuthorship W2914598286A5060010515 @default.
• W2914598286 hasAuthorship W2914598286A5062017340 @default.
• W2914598286 hasAuthorship W2914598286A5066103491 @default.
• W2914598286 hasAuthorship W2914598286A5085630057 @default.
• W2914598286 hasConcept C112613896 @default.
• W2914598286 hasConcept C127413603 @default.
• W2914598286 hasConcept C159985019 @default.
• W2914598286 hasConcept C171250308 @default.
• W2914598286 hasConcept C178790620 @default.

• next