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- W2914655032 abstract "Despite the fundamental and practical significance of the hydrogen evolution and oxidation reactions (HER/HOR), their kinetics in base remain unclear. Herein, we show that the alkaline HER/HOR kinetics can be unified by the catalytic roles of the adsorbed hydroxyl (OHad)-water-alkali metal cation (AM+) adducts, on the basis of the observations that enriching the OHad abundance via surface Ni benefits the HER/HOR; increasing the AM+ concentration only promotes the HER, while varying the identity of AM+ affects both HER/HOR. The presence of OHad-(H2O)x-AM+ in the double-layer region facilitates the OHad removal into the bulk, forming OH–-(H2O)x-AM+ as per the hard–soft acid–base theory, thereby selectively promoting the HER. It can be detrimental to the HOR as per the bifunctional mechanism, as the AM+ destabilizes the OHad, which is further supported by the CO oxidation results. This new notion may be important for alkaline electrochemistry." @default.
- W2914655032 created "2019-02-21" @default.
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- W2914655032 date "2019-01-23" @default.
- W2914655032 modified "2023-10-16" @default.
- W2914655032 title "Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts" @default.
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- W2914655032 doi "https://doi.org/10.1021/jacs.8b13228" @default.
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