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- W2914690667 abstract "The chemical and electrochemical behavior of titanium was examined in the Lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride (AlCl3-EtMeImCl) molten salt at 353.2 K. Dissolved Ti(II), as TiCl2, is stable in the 66.7–33.3 m/o composition of this melt, but shows a slight tendency to disproportionate in the 60.0–40.0 m/o melt. At low current densities, the anodic oxidation of Ti(0) does not lead to dissolved Ti(II), but to an insoluble passivating film of TiCl3. At high current densities or very positive potentials, Ti(0) is oxidized to Ti(IV); however, the electrogenerated Ti(IV) vaporizes from the melt as TiCl4(g). The electrodeposition of Ti-Al alloys was investigated at Cu rotating wire electrodes. Ti-Al alloys containing up to ~ 19 a/o titanium could be electrodeposited from saturated solutions of Ti(II) in the 66.7–33.3 m/o melt at low current densities, but the titanium content of these alloys decreased as the reduction current density was increased. The pitting potentials of these electrodeposited Ti-Al alloys exhibited a positive shift with increasing titanium content comparable to that observed for alloys prepared by sputter deposition." @default.
- W2914690667 created "2019-02-21" @default.
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- W2914690667 date "2002-01-01" @default.
- W2914690667 modified "2023-09-25" @default.
- W2914690667 title "Electrodeposition of Titanium-Aluminum Alloys in the Lewis Acidic Aluminum Chloride-1-Ethyl-3-Methylimidazolium Chloride Molten Salt" @default.
- W2914690667 doi "https://doi.org/10.1149/200219.0650pv" @default.
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