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• W2914691958 abstract "Nanocomposite polymer electrolytes (NCPE) have been prepared by blending poly(ethylene oxide) (PEO) and polyhedral oligomeric silsesquioxane-functionalized with poly(ethylene glycol) (POSS- PEG) with lithium bis(oxalate) borate (LiBOB). Different thermal, electrical and electrochemical studies exhibit promising characteristics of these polymer electrolytes, suitable as electrolytes in rechargeable lithium-ion batteries. POSS-PEG was highly compatible with PEO up to 50 wt% and resulted in single $mathbf{T}_{mathbf{g}}$ and increased ionic conductivity. The ionic conductivity of the nanocomposites increased to $3.98times 10^{-6}$ S/cm at 50 wt% of POSS-PEG by more than 2 orders of magnitude. POSS-PEG nanoparticles sustainably increased ionic conductivity without impeding chain motion of polymer and were highly compatible with PEO up to 50 wt% of POSS-PEG, which can mitigate the restriction of the amount of nanoparticles introduction. The Li/PEO-LiBOB-POSS PEG/LiFeP0 4 coin-typed cell cycled at 0.1 C shows the $1^{mathbf{st}}$ discharge capacity about 146 mAh $mathbf{g}^{-1}$ , and remains 126.2 mAh $mathbf{g}^{-1}$ on the $50^{mathbf{th}}$ cycle. Overall, these results indicate that POSS-PEG nanocomposites can be potentially useful as a new class of nanocomposite polymer electrolytes for rechargeable lithium batteries." @default.
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• W2914691958 date "2018-07-01" @default.
• W2914691958 modified "2023-09-23" @default.
• W2914691958 title "A Novel Nanocomposite Polymer Electrolyte for Application in Solid State Lithium Ion Battery" @default.
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• W2914691958 doi "https://doi.org/10.1109/nano.2018.8626268" @default.
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