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- W2914867580 abstract "In this work, we prepared two types of isostructural Ln3+-based metal–organic frameworks (LnMOFs) under solvothermal conditions, where two structurally similar pyridine-containing dicarboxylate ligands, 6-(4-carboxyphenyl)nicotinic acid and [2,2′-bipyridine]-5,5′-dicarboxylic acid, were used as the organic linkers. The as-synthesized LnMOF compounds were characterized using single-crystal X-ray diffraction (XRD), powder XRD, and thermogravimetric analysis. With the lanthanide co-doping approach, two mixed LnMOFs, Tb0.95Eu0.05cpna and Tb0.95Eu0.05bpydc, were obtained and evaluated for application as potential ratiometric luminescence thermometers. The temperature-dependent luminescence of the two materials was investigated, and their emission intensities, luminescence lifetimes, and thermometric parameters were compared. They exhibit an excellent S-shaped response for temperatures in the range of 25–300 K, with favorable relative sensitivity and temperature uncertainty. Moreover, their color changes from green at 25 K to red at 300 K, so that they are also suitable as colorimetric luminescent probes." @default.
- W2914867580 created "2019-02-21" @default.
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- W2914867580 date "2019-01-31" @default.
- W2914867580 modified "2023-10-14" @default.
- W2914867580 title "Isostructural Tb<sup>3+</sup>/Eu<sup>3+</sup> Co-Doped Metal–Organic Framework Based on Pyridine-Containing Dicarboxylate Ligands for Ratiometric Luminescence Temperature Sensing" @default.
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- W2914867580 doi "https://doi.org/10.1021/acs.inorgchem.8b03225" @default.
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