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- W2914953216 abstract "Alkynyl sulfoxides are important building blocks with a unique reactivity in organic chemistry, but only a few reliable methods have been reported to synthesize them. A novel route to access alkynyl sulfoxides is reported herein by using ethynyl benziodoxolone (EBX) reagents to trap sulfenate anions generated in situ, via a retro-Michael reaction. The reaction takes place under metal-free and mild conditions. It is compatible with aryl, heteroaryl, and alkyl sulfoxides with up to 90% yield. This practical access to alkynyl sulfoxides is expected to facilitate the application of these useful building blocks in organic synthesis." @default.
- W2914953216 created "2019-02-21" @default.
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- W2914953216 date "2019-02-07" @default.
- W2914953216 modified "2023-10-09" @default.
- W2914953216 title "Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents" @default.
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- W2914953216 doi "https://doi.org/10.1021/acs.joc.9b00050" @default.
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