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• W2914954927 abstract "A silicon-aluminum heterocycle LAl(SiH2SiH2)2AlL (L = PhC(NtBu)2) (1) was prepared. Compound 1 exhibits a unique (N2Al)2(SiH2)4 centrosymmetric six-membered ring structure with a chair conformation, which is comparable with that of cyclohexane. Furthermore, two intermediate analogues, silylene-alane adduct LSi(AlMe3)-Si(AlMe3)L (2) and silylene-alane oxidative product [LAlHSiH2Mes]2 (3) were obtained. Compound 3 has an interesting arrangement of an Al-H and an SiH2 unit, which are in close vicinity to each other. 3 might be important to function as a catalyst, due to the already activated bridging Al-H bonds." @default.
• W2914954927 created "2019-02-21" @default.
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• W2914954927 date "2019-01-01" @default.
• W2914954927 modified "2023-10-14" @default.
• W2914954927 title "(PhC(N<i>t</i>Bu)₂Al)₂(SiH₂)₄ six-membered heterocycle: comparable in structure to cyclohexane" @default.
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• W2914954927 doi "https://doi.org/10.1039/c8cc10124h" @default.
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