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- W2914959095 abstract "Terminal acetals were selectively synthesized from various unbiased aliphatic terminal alkenes and 1,2-, 1,3-, or 1,4-diols using a PdCl2(MeCN)2/CuCl catalyst system in the presence of p-toluquinone under 1 atm of O2 and mild reaction conditions. The slow addition of terminal alkenes suppressed the isomerization to internal alkenes successfully. Electron-deficient cyclic alkenes, such as p-toluquinone, were key additives to enhance the catalytic activity and the anti-Markovnikov selectivity. The halogen groups in the alkenes were found to operate as directing groups, suppressing isomerization and increasing the selectivity efficiently." @default.
- W2914959095 created "2019-02-21" @default.
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- W2914959095 date "2019-01-21" @default.
- W2914959095 modified "2023-10-14" @default.
- W2914959095 title "Palladium-Catalyzed Aerobic Anti-Markovnikov Oxidation of Aliphatic Alkenes to Terminal Acetals" @default.
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- W2914959095 doi "https://doi.org/10.1021/acs.joc.8b02919" @default.
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