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• W291498265 abstract "Taking into account the biological significance of electron-exchange properties of nucleic heterocycles, we have studied the electrochemical reduction of their simplest model compound i.e. the pyrimidine, using drop-time controlled polarography and cyclic voltammetry on mercury drop and stationary vitreous carbon electrode. The characteristics of the different reduction waves have been studied with respect to the different experimental parameters: pH, nature and concentration of buffer solutions, pyrimidine concentration, mercury flow and mechanically controlled drop-time, temperature, nature of the electrode, etc. The analysis of the experimental data is discussed in terms of energetical significance of the phenomena observed. Evidence is given of a chemical association step, possibly a dimerization, occuring between the two reduction steps in acid media." @default.
• W291498265 created "2016-06-24" @default.
• W291498265 creator A5036977799 @default.
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• W291498265 date "1971-01-01" @default.
• W291498265 modified "2023-10-01" @default.
• W291498265 title "Electrochemical Properties of Model Compounds of Nucleic Heterocycles in Aqueous Solutions" @default.
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• W291498265 doi "https://doi.org/10.1007/978-3-0348-5848-9_62" @default.
• W291498265 hasPublicationYear "1971" @default.
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