Matches in SemOpenAlex for { <https://semopenalex.org/work/W2915533182> ?p ?o ?g. }
- W2915533182 endingPage "943" @default.
- W2915533182 startingPage "934" @default.
- W2915533182 abstract "In this communication, experimental hydrate dissociation data for methane + tetrahydrofuran (THF) (0.03 and 0.0555 mole fractions in aqueous solution) + cyclopentane (CP) + water systems are reported in the temperature range from 294.8 to 301.3 K and pressure range from 1.91 to 4.95 MPa, which are measured using an isochoric pressure-search method. Other experimental data were collected from the literature. Then a thermodynamic model for four-phase equilibria, hydrate (H)–aqueous liquid (Lw)–organic liquid (La)–vapor/gas (V), systems composed of water, methane (CH4), carbon dioxide (CO2), and/or CP was developed. The thermodynamic model is based on the solid solution theory of van der Waals–Platteeuw (vdW-P) for the hydrate phase and Peng–Robinson equation of state (P-R EOS) for vapor/gas phase. For calculating the activity coefficient of water and THF in the aqueous phase, the universal quasichemical (UNIQUAC) functional-group activity coefficient (UNIFAC) model is also used. The Langmuir constants of THF and CP are calculated by using the Parrish and Prausnitz equations under this assumption that THF and CP occupy large cavity and CH4 occupies small cavity of structure II hydrate. The calculated Langmuir constants are extended to other systems. Using the vdW-P model, PR EOS, and calculated Langmuir constants, the binary interaction parameters for van Laar, nonrandom two-liquid, and UNIFAC models are calculated. Results show that THF and CP decrease the equilibrium pressure, and by adding both THF and CP into the pure water; these mixtures show better promotion effects in comparison to the individual ones." @default.
- W2915533182 created "2019-03-02" @default.
- W2915533182 creator A5003607074 @default.
- W2915533182 creator A5018791966 @default.
- W2915533182 creator A5037786093 @default.
- W2915533182 date "2019-02-22" @default.
- W2915533182 modified "2023-10-09" @default.
- W2915533182 title "Thermodynamic Stability Conditions of Clathrate Hydrates in Methane/Carbon Dioxide + Tetrahydrofuran + Cyclopentane + Water Systems: Experimental Measurement and Modeling" @default.
- W2915533182 cites W1964775215 @default.
- W2915533182 cites W1990010494 @default.
- W2915533182 cites W1994369177 @default.
- W2915533182 cites W2013983032 @default.
- W2915533182 cites W2024571724 @default.
- W2915533182 cites W2026988136 @default.
- W2915533182 cites W2035601369 @default.
- W2915533182 cites W2039921149 @default.
- W2915533182 cites W2049024397 @default.
- W2915533182 cites W2055801266 @default.
- W2915533182 cites W2060451324 @default.
- W2915533182 cites W2060829511 @default.
- W2915533182 cites W2069497729 @default.
- W2915533182 cites W2086318904 @default.
- W2915533182 cites W2087645035 @default.
- W2915533182 cites W2097513673 @default.
- W2915533182 cites W2105730493 @default.
- W2915533182 cites W2115528391 @default.
- W2915533182 cites W2129288307 @default.
- W2915533182 cites W2132940782 @default.
- W2915533182 cites W2145605621 @default.
- W2915533182 cites W2317454748 @default.
- W2915533182 cites W2323549983 @default.
- W2915533182 cites W2328065600 @default.
- W2915533182 cites W2332011673 @default.
- W2915533182 cites W2343039269 @default.
- W2915533182 cites W2526341713 @default.
- W2915533182 cites W4253642401 @default.
- W2915533182 doi "https://doi.org/10.1021/acs.jced.8b00804" @default.
- W2915533182 hasPublicationYear "2019" @default.
- W2915533182 type Work @default.
- W2915533182 sameAs 2915533182 @default.
- W2915533182 citedByCount "5" @default.
- W2915533182 countsByYear W29155331822020 @default.
- W2915533182 countsByYear W29155331822022 @default.
- W2915533182 countsByYear W29155331822023 @default.
- W2915533182 crossrefType "journal-article" @default.
- W2915533182 hasAuthorship W2915533182A5003607074 @default.
- W2915533182 hasAuthorship W2915533182A5018791966 @default.
- W2915533182 hasAuthorship W2915533182A5037786093 @default.
- W2915533182 hasConcept C100402318 @default.
- W2915533182 hasConcept C121332964 @default.
- W2915533182 hasConcept C126061179 @default.
- W2915533182 hasConcept C147789679 @default.
- W2915533182 hasConcept C170961132 @default.
- W2915533182 hasConcept C178790620 @default.
- W2915533182 hasConcept C184651966 @default.
- W2915533182 hasConcept C185592680 @default.
- W2915533182 hasConcept C187434265 @default.
- W2915533182 hasConcept C2776701986 @default.
- W2915533182 hasConcept C2778556512 @default.
- W2915533182 hasConcept C2780471494 @default.
- W2915533182 hasConcept C2781060337 @default.
- W2915533182 hasConcept C32909587 @default.
- W2915533182 hasConcept C516920438 @default.
- W2915533182 hasConcept C91556481 @default.
- W2915533182 hasConcept C97355855 @default.
- W2915533182 hasConceptScore W2915533182C100402318 @default.
- W2915533182 hasConceptScore W2915533182C121332964 @default.
- W2915533182 hasConceptScore W2915533182C126061179 @default.
- W2915533182 hasConceptScore W2915533182C147789679 @default.
- W2915533182 hasConceptScore W2915533182C170961132 @default.
- W2915533182 hasConceptScore W2915533182C178790620 @default.
- W2915533182 hasConceptScore W2915533182C184651966 @default.
- W2915533182 hasConceptScore W2915533182C185592680 @default.
- W2915533182 hasConceptScore W2915533182C187434265 @default.
- W2915533182 hasConceptScore W2915533182C2776701986 @default.
- W2915533182 hasConceptScore W2915533182C2778556512 @default.
- W2915533182 hasConceptScore W2915533182C2780471494 @default.
- W2915533182 hasConceptScore W2915533182C2781060337 @default.
- W2915533182 hasConceptScore W2915533182C32909587 @default.
- W2915533182 hasConceptScore W2915533182C516920438 @default.
- W2915533182 hasConceptScore W2915533182C91556481 @default.
- W2915533182 hasConceptScore W2915533182C97355855 @default.
- W2915533182 hasIssue "3" @default.
- W2915533182 hasLocation W29155331821 @default.
- W2915533182 hasOpenAccess W2915533182 @default.
- W2915533182 hasPrimaryLocation W29155331821 @default.
- W2915533182 hasRelatedWork W1992242294 @default.
- W2915533182 hasRelatedWork W2094232447 @default.
- W2915533182 hasRelatedWork W2096243998 @default.
- W2915533182 hasRelatedWork W2322204562 @default.
- W2915533182 hasRelatedWork W2328065600 @default.
- W2915533182 hasRelatedWork W2750135505 @default.
- W2915533182 hasRelatedWork W2783307370 @default.
- W2915533182 hasRelatedWork W3107444284 @default.
- W2915533182 hasRelatedWork W3162423134 @default.
- W2915533182 hasRelatedWork W2980767953 @default.
- W2915533182 hasVolume "64" @default.
- W2915533182 isParatext "false" @default.