FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2915829496> ?p ?o ?g. }

• W2915829496 endingPage "1713" @default.
• W2915829496 startingPage "1703" @default.
• W2915829496 abstract "Biobased, self-organizing molecules are of considerable interest as functional materials due to their structural versatility, sophisticated nanoarchitectures, and sustainable biosynthesis. Here, we study the self-assembly of a systematic series of bioconjugate sophorolipid-functionalized zinc porphyrin complexes with potential applications in optoelectronic devices. Our results provide insight into the molecular features that control the polymerization pathway, in particular the influence of carbohydrate chirality and noncovalent hydrogen-bonding on biosurfactant-driven self-organization of sophisticated light-absorbing supramolecular polymers. The self-assembly process is driven by a combination of hydrogen-bond, steric, and π-π interactions. Compounds under investigation were synthesized to examine the influence of peripheral chiral carbohydrate hydrogen bonding on chromophore aggregation and physicochemical properties through selective acetylation of the sophorose moiety. In dilute methanol/water solution, we found that excitonically coupled helical structures form by strong carbohydrate hydrogen-bonding interactions, in contrast to weakly coupled J-type aggregate formation with acetyl-group substitution of sugar hydroxyl moieties. Temperature-dependent UV/vis absorption and circular dichroism revealed that supramolecular polymerization proceeds through a cooperative mechanism of self-assembly for compounds bearing free OH groups capable of forming hydrogen-bond interactions. In contrast, per-acetylation of the sophorolipid's sugar group leads to micellar aggregation that is governed by a sterically driven isodesmic (noncooperative) assembly mechanism." @default.
• W2915829496 created "2019-03-02" @default.
• W2915829496 creator A5020923956 @default.
• W2915829496 creator A5049257620 @default.
• W2915829496 creator A5079993358 @default.
• W2915829496 creator A5081807028 @default.
• W2915829496 date "2019-02-28" @default.
• W2915829496 modified "2023-10-13" @default.
• W2915829496 title "Cooperative Self-Assembly of Helical Exciton-Coupled Biosurfactant-Functionalized Porphyrin Chromophores" @default.
• W2915829496 cites W1218544360 @default.
• W2915829496 cites W1615871248 @default.
• W2915829496 cites W1828725123 @default.
• W2915829496 cites W1901887072 @default.
• W2915829496 cites W1908616358 @default.
• W2915829496 cites W1963531331 @default.
• W2915829496 cites W1967453978 @default.
• W2915829496 cites W1968148714 @default.
• W2915829496 cites W1968566504 @default.
• W2915829496 cites W1968611493 @default.
• W2915829496 cites W1977054502 @default.
• W2915829496 cites W1977685010 @default.
• W2915829496 cites W1978475111 @default.
• W2915829496 cites W1980108884 @default.
• W2915829496 cites W1985298358 @default.
• W2915829496 cites W1987286232 @default.
• W2915829496 cites W1988066093 @default.
• W2915829496 cites W1992679438 @default.
• W2915829496 cites W1994222180 @default.
• W2915829496 cites W1996306479 @default.
• W2915829496 cites W2002742052 @default.
• W2915829496 cites W2008914462 @default.
• W2915829496 cites W2013865111 @default.
• W2915829496 cites W2013883394 @default.
• W2915829496 cites W2017220615 @default.
• W2915829496 cites W2017562779 @default.
• W2915829496 cites W2023557482 @default.
• W2915829496 cites W2025361400 @default.
• W2915829496 cites W2034078366 @default.
• W2915829496 cites W2051394400 @default.
• W2915829496 cites W2058973852 @default.
• W2915829496 cites W2066736067 @default.
• W2915829496 cites W2075129724 @default.
• W2915829496 cites W2076025950 @default.
• W2915829496 cites W2078398728 @default.
• W2915829496 cites W2097714181 @default.
• W2915829496 cites W2102715499 @default.
• W2915829496 cites W2108044367 @default.
• W2915829496 cites W2110196431 @default.
• W2915829496 cites W2112216863 @default.
• W2915829496 cites W2127355460 @default.
• W2915829496 cites W2149950518 @default.
• W2915829496 cites W2154338418 @default.
• W2915829496 cites W2192976161 @default.
• W2915829496 cites W2217782303 @default.
• W2915829496 cites W2313052568 @default.
• W2915829496 cites W2316632085 @default.
• W2915829496 cites W2322555756 @default.
• W2915829496 cites W2329541400 @default.
• W2915829496 cites W2400800461 @default.
• W2915829496 cites W2403368260 @default.
• W2915829496 cites W2434410156 @default.
• W2915829496 cites W2531647489 @default.
• W2915829496 cites W2531773587 @default.
• W2915829496 cites W2561239809 @default.
• W2915829496 cites W2586930577 @default.
• W2915829496 cites W2600533839 @default.
• W2915829496 cites W2601700491 @default.
• W2915829496 cites W2605857455 @default.
• W2915829496 cites W2615150721 @default.
• W2915829496 cites W2615246133 @default.
• W2915829496 cites W2724419348 @default.
• W2915829496 cites W2734887970 @default.
• W2915829496 cites W2750594996 @default.
• W2915829496 cites W2766527333 @default.
• W2915829496 cites W2767372961 @default.
• W2915829496 cites W2795733505 @default.
• W2915829496 cites W2806124901 @default.
• W2915829496 cites W2890050971 @default.
• W2915829496 doi "https://doi.org/10.1021/acsabm.9b00086" @default.
• W2915829496 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35026905" @default.
• W2915829496 hasPublicationYear "2019" @default.
• W2915829496 type Work @default.
• W2915829496 sameAs 2915829496 @default.
• W2915829496 citedByCount "10" @default.
• W2915829496 countsByYear W29158294962019 @default.
• W2915829496 countsByYear W29158294962020 @default.
• W2915829496 countsByYear W29158294962021 @default.
• W2915829496 countsByYear W29158294962022 @default.
• W2915829496 countsByYear W29158294962023 @default.
• W2915829496 crossrefType "journal-article" @default.
• W2915829496 hasAuthorship W2915829496A5020923956 @default.
• W2915829496 hasAuthorship W2915829496A5049257620 @default.
• W2915829496 hasAuthorship W2915829496A5079993358 @default.
• W2915829496 hasAuthorship W2915829496A5081807028 @default.
• W2915829496 hasConcept C112887158 @default.
• W2915829496 hasConcept C121332964 @default.
• W2915829496 hasConcept C124668440 @default.
• W2915829496 hasConcept C133571119 @default.

• next