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- W2916117956 abstract "Die Ergebnisse der EMK-Messungen [1], die sich nur mit der Annahme von monomeren Hydroxoaluminationen [Al(OH)4]− deuten lassen, konnten durch den als konstant gefundenen Wert des Diffusionskoeffizienten bestätigt werden. Da sich der Diffusionskoeffizient mit dem Molverhältnis [OH−]/[Al] der Lösungen nicht verändert, kann die Existenz von Polyanionen, auch in geringer Konzentration, ausgeschlossen werden. Der für 25 °C ermittelte Diffusionskoeffizient hat den Wert D = 0,748 [cm2 d−1]. Die Ionenleitfähigkeit des Aluminations beträgt für 25 °C l0 = 325 [cm2 Ω−1 · val−1]. The results of EMF measurements [1] are in agreement with the coefficient of diffusion found to be constant and independent of the [OH−]/[Al]-ratio in the hydroxo aluminate solutions. Therefore in sodium aluminate solutions the existence of only monomeric hydroxo aluminate ions [Al(OH)4]− was proved. At 25 °C the value of the coefficient of diffusion is D = 0.7[4] 8 [cm2 d−1]. The limiting equivalent conductivity of the aluminate ion proved to be l0 = 325 [cm2 Ω−1 · val−1]." @default.
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- W2916117956 date "1965-05-01" @default.
- W2916117956 modified "2023-09-24" @default.
- W2916117956 title "Über den Lösungszustand des Natriumhydroxoaluminates 2. Mitteilung" @default.
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- W2916117956 doi "https://doi.org/10.1002/bbpc.19650690309" @default.
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