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- W2916276475 abstract "Abstract 1‐propanol is a primary alcohol extensively used in the pharmaceutical, chemical, and food industries. It has been also found as a contaminant in the atmosphere and is considered a model compound to mimic the behavior and fate of aliphatic alcohols exposed to environmental conditions. In order to understand that role of relevant variables, this paper presents results obtained with a simple experimental set‐up to investigate the reactivity of 1‐propanol under mild oxidizing conditions. Coupling this system with CE‐C 4 D allowed the quantification of the carboxylic acids formed. For the described experiments, aqueous solutions of 1‐propanol were placed inside a photoreactor and oxidized upon the addition of TiO 2 and/or H 2 O 2 . According to the described results, the addition of H 2 O 2 (0.1% w/w) was the most significant variable, roughly tripled the amount of carboxylic acids generated and led to the conversion of up to 70% of the initially available 1‐propanol (1 mmol/L). More importantly, the reaction yielded the formation (within 10 min) of propionate (50 µmol/L), acetate (400 µmol/L), formate (50 µmol/L), and malonate (200 µmol/L). The latter is critically important because it represents the first example of the photochemical oxidation of both terminal carbons of the C 3 ‐chain of 1‐propanol under mild conditions, and opens new avenues for the production of this important chemical building block." @default.
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- W2916276475 date "2019-03-06" @default.
- W2916276475 modified "2023-10-11" @default.
- W2916276475 title "Photochemical and photocatalytic degradation of 1‐propanol using UV/H<sub>2</sub>O<sub>2</sub>: Identification of malonate as byproduct" @default.
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- W2916276475 doi "https://doi.org/10.1002/elps.201900001" @default.
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