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• W2916394016 endingPage "3905" @default.
• W2916394016 startingPage "3893" @default.
• W2916394016 abstract "The synthesis, structures, and properties of a new calix[4]arene ligand with an appended salicylaldimine unit (H4L = 25-[2-((2-methylphenol)imino)ethoxy]-26,27,28-trihydroxy-calix[4]arene) and four lanthanide complexes (HNEt3)[Ln2(HL)(L)] (Ln = SmIII (4), EuIII (5), GdIII (6), and TbIII (7)) are reported. X-ray crystallographic analysis (for 4 and 6) reveals an isostructural series of dimeric complexes with a triply-bridged NO3Ln(μ-O)2(OHO)LnO3N core and two seven coordinated lanthanide ions. According to UV-vis spectrometric titrations in MeCN and ESI-MS the dimeric nature is maintained in solution. The apparent stability constants range between log K = 5.8 and 6.3. The appended salicylaldimines sensitize EuIII and TbIII emission (λexc 311 nm) in the solid state or immersed in a polycarbonate glass at 77 K (for 5, 7) and at 295 K (for 7)." @default.
• W2916394016 created "2019-03-02" @default.
• W2916394016 creator A5005620103 @default.
• W2916394016 creator A5018594410 @default.
• W2916394016 creator A5022987679 @default.
• W2916394016 creator A5028588657 @default.
• W2916394016 creator A5033664830 @default.
• W2916394016 creator A5040940116 @default.
• W2916394016 creator A5067286698 @default.
• W2916394016 date "2019-01-01" @default.
• W2916394016 modified "2023-10-03" @default.
• W2916394016 title "Dinuclear lanthanide complexes supported by a hybrid salicylaldiminato/calix[4]arene-ligand: synthesis, structure, and magnetic and luminescence properties of (HNEt₃)[Ln₂(HL)(L)] (Ln = Sm^III, Eu^III, Gd^III, Tb^III)" @default.
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