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• W2916578218 abstract "Four [Ag–Ag]2+ unit-encapsulated trimetallic cages 1–4 were synthesized from one new tripodal ligand L and silver salts in different solvent systems by a one-pot method. The formation of coordination cages occurred simultaneously with the condensation of amino groups and ketone. The remarkable structural feature of cages 1–4 is their spontaneous incorporation of [Ag–Ag]2+ cationic units. Moreover, the argentophilic interactions are modulated by the uncoordinated amino substituents. The study herein shows that modification and subtle changes of the cage structures could be realized by a one-pot synthetic method." @default.
• W2916578218 created "2019-03-02" @default.
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• W2916578218 date "2019-02-20" @default.
• W2916578218 modified "2023-10-12" @default.
• W2916578218 title "[Ag–Ag]²⁺ Unit-Encapsulated Trimetallic Cages: One-Pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents" @default.
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• W2916578218 doi "https://doi.org/10.1021/acs.inorgchem.8b03388" @default.
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• W2916578218 hasPublicationYear "2019" @default.
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