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• W2916802672 abstract "The classical notion of the coalescence of two droplets of the same radius R is that surface tension drives an initially singular flow. In this Letter we show, using molecular dynamics simulations of coalescing water nanodroplets, that after single or multiple bridges form due to the presence of thermal capillary waves, the bridge growth commences in a thermal regime. Here, the bridges expand linearly in time much faster than the viscous-capillary speed due to collective molecular jumps near the bridge fronts. Transition to the classical hydrodynamic regime only occurs once the bridge radius exceeds a thermal length scale lT∼R.Received 24 May 2018Revised 11 September 2018DOI:https://doi.org/10.1103/PhysRevLett.122.104501Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.Published by the American Physical SocietyPhysics Subject Headings (PhySH)Research AreasDrop coalescenceInterfacial flowsTechniquesMolecular dynamicsFluid Dynamics" @default.
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• W2916802672 date "2019-03-13" @default.
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• W2916802672 title "Droplet Coalescence is Initiated by Thermal Motion" @default.
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• W2916802672 doi "https://doi.org/10.1103/physrevlett.122.104501" @default.
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