Matches in SemOpenAlex for { <https://semopenalex.org/work/W2916855237> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2916855237 abstract "In the first year of our present program, we investigated a chemical CW source of carbyne radicals suitable for kinetic studies in fast-flow reactors. The approach used alkali metal atoms (M = Na or K) to successively abstract halogen (X = Br or C/ell/) atoms from a haloform molecule, producing the CH radical and three alkali halide molecules. Early in the second year, attempts to observe CH reacting with O/sub 2/, H/sub 2/, and N/sub 2/ produced mixed results, suggesting that better separation between CH production and reaction zones was necessary. A pre-reactor assembly that permits variation of nearly all source parameters independent of main reactor conditions was constructed. The third year of the program yielded high-quality kinetic data for five CH reactions (CH + Cl/sub 2/, N/sub 2/O, CH/sub 4/, O/sub 2/, and H/sub 2/), and preliminary results for three others (D/sub 2/, NO and N/sub 2/) at 2 Torr and 290/degree/K. This was the first study of the CH + Cl/sub 2/ reaction. In addition, we made preliminary observations of significant OH production from both the CH + O/sub 2/ and NO reactions. Initial attempts to operate at higher temperatures (up to 1100 K) revealed a needed designmore » change in the source. Plans for the fourth year of this effort include completing a study of CH + N/sub 2/, H/sub 2/ and CO reaction kinetics, as a function of temperature, determining the OH yields for CH + O/sub 2/ and NO, and investigating mechanistically related reactions, such as /sup 12/CH + /sup 13/CO ..-->.. /sup 13/CH + /sup 12/CO. 20 refs., 8 figs.« less" @default.
- W2916855237 created "2019-03-02" @default.
- W2916855237 creator A5023485550 @default.
- W2916855237 creator A5049382805 @default.
- W2916855237 creator A5064196731 @default.
- W2916855237 date "1988-01-01" @default.
- W2916855237 modified "2023-09-27" @default.
- W2916855237 title "A program to study CH reactions relevant to combustion/gasification processes: Final report, July 1986-July 1987" @default.
- W2916855237 hasPublicationYear "1988" @default.
- W2916855237 type Work @default.
- W2916855237 sameAs 2916855237 @default.
- W2916855237 citedByCount "0" @default.
- W2916855237 crossrefType "journal-article" @default.
- W2916855237 hasAuthorship W2916855237A5023485550 @default.
- W2916855237 hasAuthorship W2916855237A5049382805 @default.
- W2916855237 hasAuthorship W2916855237A5064196731 @default.
- W2916855237 hasConcept C113196181 @default.
- W2916855237 hasConcept C121332964 @default.
- W2916855237 hasConcept C139066938 @default.
- W2916855237 hasConcept C147789679 @default.
- W2916855237 hasConcept C148898269 @default.
- W2916855237 hasConcept C171560689 @default.
- W2916855237 hasConcept C178790620 @default.
- W2916855237 hasConcept C179104552 @default.
- W2916855237 hasConcept C185592680 @default.
- W2916855237 hasConcept C198091228 @default.
- W2916855237 hasConcept C2780263894 @default.
- W2916855237 hasConcept C36663273 @default.
- W2916855237 hasConcept C46062151 @default.
- W2916855237 hasConcept C62520636 @default.
- W2916855237 hasConceptScore W2916855237C113196181 @default.
- W2916855237 hasConceptScore W2916855237C121332964 @default.
- W2916855237 hasConceptScore W2916855237C139066938 @default.
- W2916855237 hasConceptScore W2916855237C147789679 @default.
- W2916855237 hasConceptScore W2916855237C148898269 @default.
- W2916855237 hasConceptScore W2916855237C171560689 @default.
- W2916855237 hasConceptScore W2916855237C178790620 @default.
- W2916855237 hasConceptScore W2916855237C179104552 @default.
- W2916855237 hasConceptScore W2916855237C185592680 @default.
- W2916855237 hasConceptScore W2916855237C198091228 @default.
- W2916855237 hasConceptScore W2916855237C2780263894 @default.
- W2916855237 hasConceptScore W2916855237C36663273 @default.
- W2916855237 hasConceptScore W2916855237C46062151 @default.
- W2916855237 hasConceptScore W2916855237C62520636 @default.
- W2916855237 hasLocation W29168552371 @default.
- W2916855237 hasOpenAccess W2916855237 @default.
- W2916855237 hasPrimaryLocation W29168552371 @default.
- W2916855237 hasRelatedWork W1988153309 @default.
- W2916855237 hasRelatedWork W2003394514 @default.
- W2916855237 hasRelatedWork W2022384484 @default.
- W2916855237 hasRelatedWork W2024057193 @default.
- W2916855237 hasRelatedWork W2039419372 @default.
- W2916855237 hasRelatedWork W2056199246 @default.
- W2916855237 hasRelatedWork W2056995211 @default.
- W2916855237 hasRelatedWork W2092359453 @default.
- W2916855237 hasRelatedWork W2233106585 @default.
- W2916855237 hasRelatedWork W2285447633 @default.
- W2916855237 hasRelatedWork W23452841 @default.
- W2916855237 hasRelatedWork W2916762130 @default.
- W2916855237 hasRelatedWork W2949176786 @default.
- W2916855237 hasRelatedWork W2949731154 @default.
- W2916855237 hasRelatedWork W2950485596 @default.
- W2916855237 hasRelatedWork W2951493657 @default.
- W2916855237 hasRelatedWork W2951758936 @default.
- W2916855237 hasRelatedWork W2952794710 @default.
- W2916855237 hasRelatedWork W302690440 @default.
- W2916855237 hasRelatedWork W749533358 @default.
- W2916855237 isParatext "false" @default.
- W2916855237 isRetracted "false" @default.
- W2916855237 magId "2916855237" @default.
- W2916855237 workType "article" @default.