FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2917020114> ?p ?o ?g. }

• W2917020114 endingPage "1056" @default.
• W2917020114 startingPage "1045" @default.
• W2917020114 abstract "Reactions of alkali salts (nitrates, sulfates, carbonates, halides, borates) play a key role in the low temperature feed conversion occurring at the cold cap during processing of Hanford Low Activity Waste (LAW) glass melters. An alkali salt phase can sometimes form, and preferentially incorporate radionuclides of Cs, Cl, I, and Tc. During melting of the slurry feed, some of the feed components sequentially break down with increasing temperature to form gases (i.e., nitrates ➔ NOx, carbonates ➔ CO2, and boric acid ➔ H2O) or partially volatilize (halides). Sulfate, however, tends not to volatilize but has limited solubility in the final borosilicate glass waste form. To improve understanding of these low temperature processes and their composition dependencies, a scoping study was undertaken to synthesize salt systems that remain amorphous at room temperature, thus facilitating structural study. Melts of equimolar ratios of K2SO4-ZnSO4 (a known ionic glass-forming system) with added nitrates, halides, or carbonates, were melted and quenched. Some of the materials formed single phase glasses and some underwent crystallization upon quenching. Characterization of these quenched materials by thermal analysis, infrared absorption, and diffraction was performed. Addition of other anions to the sulfate base glass resulted in a distortion of the sulfate tetrahedron, as evidenced by infrared absorption. Carbonates strongly promoted crystallization, mostly of carbonate phases. Nitrates promoted crystallization of ZnO, and the nitrate volatilized with some incorporating into the glass. Halides tended to incorporate into the glass, but the small (F) and large (I) halogens promoted crystallization of sulfate-containing crystals, while moderate sized (Cl) halogens produced single-phase ionic glasses." @default.
• W2917020114 created "2019-03-02" @default.
• W2917020114 creator A5002131321 @default.
• W2917020114 creator A5019920861 @default.
• W2917020114 creator A5076183522 @default.
• W2917020114 date "2019-02-21" @default.
• W2917020114 modified "2023-10-11" @default.
• W2917020114 title "Structural Characterization of Ternary Salt Melts for Low Activity Waste Applications" @default.
• W2917020114 cites W1671711997 @default.
• W2917020114 cites W1915897003 @default.
• W2917020114 cites W1977942431 @default.
• W2917020114 cites W1995410543 @default.
• W2917020114 cites W2003896874 @default.
• W2917020114 cites W2010161245 @default.
• W2917020114 cites W2010870210 @default.
• W2917020114 cites W2013551530 @default.
• W2917020114 cites W2016081043 @default.
• W2917020114 cites W2021059656 @default.
• W2917020114 cites W2021489634 @default.
• W2917020114 cites W2032138717 @default.
• W2917020114 cites W2052188505 @default.
• W2917020114 cites W2056294493 @default.
• W2917020114 cites W2056865625 @default.
• W2917020114 cites W2058037853 @default.
• W2917020114 cites W2063197669 @default.
• W2917020114 cites W2065174191 @default.
• W2917020114 cites W2078354533 @default.
• W2917020114 cites W2088521685 @default.
• W2917020114 cites W2145150743 @default.
• W2917020114 cites W2162834691 @default.
• W2917020114 cites W2242604911 @default.
• W2917020114 cites W2319316552 @default.
• W2917020114 cites W2338377512 @default.
• W2917020114 cites W2396319965 @default.
• W2917020114 cites W2484479683 @default.
• W2917020114 cites W2602023109 @default.
• W2917020114 cites W4237052244 @default.
• W2917020114 cites W4243669927 @default.
• W2917020114 doi "https://doi.org/10.1557/adv.2019.136" @default.
• W2917020114 hasPublicationYear "2019" @default.
• W2917020114 type Work @default.
• W2917020114 sameAs 2917020114 @default.
• W2917020114 citedByCount "3" @default.
• W2917020114 countsByYear W29170201142019 @default.
• W2917020114 countsByYear W29170201142022 @default.
• W2917020114 countsByYear W29170201142023 @default.
• W2917020114 crossrefType "journal-article" @default.
• W2917020114 hasAuthorship W2917020114A5002131321 @default.
• W2917020114 hasAuthorship W2917020114A5019920861 @default.
• W2917020114 hasAuthorship W2917020114A5076183522 @default.
• W2917020114 hasBestOaLocation W29170201142 @default.
• W2917020114 hasConcept C127413603 @default.
• W2917020114 hasConcept C145653223 @default.
• W2917020114 hasConcept C155574463 @default.
• W2917020114 hasConcept C171560689 @default.
• W2917020114 hasConcept C178790620 @default.
• W2917020114 hasConcept C179104552 @default.
• W2917020114 hasConcept C185592680 @default.
• W2917020114 hasConcept C191897082 @default.
• W2917020114 hasConcept C192562407 @default.
• W2917020114 hasConcept C198091228 @default.
• W2917020114 hasConcept C199289684 @default.
• W2917020114 hasConcept C203036418 @default.
• W2917020114 hasConcept C206802598 @default.
• W2917020114 hasConcept C2778343803 @default.
• W2917020114 hasConcept C2780026712 @default.
• W2917020114 hasConcept C2780263894 @default.
• W2917020114 hasConcept C42360764 @default.
• W2917020114 hasConcept C46062151 @default.
• W2917020114 hasConceptScore W2917020114C127413603 @default.
• W2917020114 hasConceptScore W2917020114C145653223 @default.
• W2917020114 hasConceptScore W2917020114C155574463 @default.
• W2917020114 hasConceptScore W2917020114C171560689 @default.
• W2917020114 hasConceptScore W2917020114C178790620 @default.
• W2917020114 hasConceptScore W2917020114C179104552 @default.
• W2917020114 hasConceptScore W2917020114C185592680 @default.
• W2917020114 hasConceptScore W2917020114C191897082 @default.
• W2917020114 hasConceptScore W2917020114C192562407 @default.
• W2917020114 hasConceptScore W2917020114C198091228 @default.
• W2917020114 hasConceptScore W2917020114C199289684 @default.
• W2917020114 hasConceptScore W2917020114C203036418 @default.
• W2917020114 hasConceptScore W2917020114C206802598 @default.
• W2917020114 hasConceptScore W2917020114C2778343803 @default.
• W2917020114 hasConceptScore W2917020114C2780026712 @default.
• W2917020114 hasConceptScore W2917020114C2780263894 @default.
• W2917020114 hasConceptScore W2917020114C42360764 @default.
• W2917020114 hasConceptScore W2917020114C46062151 @default.
• W2917020114 hasIssue "17-18" @default.
• W2917020114 hasLocation W29170201141 @default.
• W2917020114 hasLocation W29170201142 @default.
• W2917020114 hasOpenAccess W2917020114 @default.
• W2917020114 hasPrimaryLocation W29170201141 @default.
• W2917020114 hasRelatedWork W107427781 @default.
• W2917020114 hasRelatedWork W2003901887 @default.
• W2917020114 hasRelatedWork W2016584486 @default.
• W2917020114 hasRelatedWork W2059614870 @default.
• W2917020114 hasRelatedWork W2076702115 @default.
• W2917020114 hasRelatedWork W2107814784 @default.

• next