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• W2917192937 abstract "We have succeeded in fabrication of lead-halide single crystalline heterostructures by physical vapor deposition. By coevaporating CH3NH3I and PbI2 onto atomically flat CH3NH3PbBr3 (001) surfaces at room temperature, pseudomorphic perovskite alloy CH3NH3Pb(Br1−xIx)3 thin films are epitaxially formed. Formation of alloys proceeds by interdiffusion of I and Br ions via halide ion vacancies. Continuous ion exchange results in exponential decay in iodine composition x with a time constant of about one month. We suggest that large lattice mismatch between CH3NH3PbI3 and CH3NH3PbBr3 may accelerate alloying driven by the ion migration." @default.
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• W2917192937 date "2019-02-22" @default.
• W2917192937 modified "2023-10-16" @default.
• W2917192937 title "Epitaxial CH₃NH₃Pb(Br_1−<i>x</i>I_<i>x</i>)₃ thin films on CH₃NH₃PbBr₃ single crystal substrates formed by physical vapor deposition" @default.
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• W2917192937 doi "https://doi.org/10.7567/1347-4065/aafed0" @default.
• W2917192937 hasPublicationYear "2019" @default.
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