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- W2917265566 abstract "The synthesis of multinary oxide-nitride spinels, γ-Si2AlON3, γ-Si1.9Al1.1O1.1N2.9, γ-SiAl2O2N2 and γ-Si0.9Al2.1O2.1N1.9, is presented. These phases belong to a solid solution series γ-Si3-xAlxOxN4-x between the new high-pressure modification of silicon nitride (γ-Si3N4) and a hypothetical γ-Al3O3N. The spinel-sialons were characterized using optical and scanning electron microscopy, electron probe microanalysis, X-ray powder diffractometry and micro-Raman spectroscopy. The spinel structure was also investigated using techniques of ab-initio electronic structure theory, revealing a bulk modulus B0 of about 270 GPa. The Vickers microhardness of γ-Si2AlON3 was measured to be 27 GPa and a mean fracture toughness of 4.6 Mpa m1/2 was obtained from the post-indentation crack length (ICL) method. These excellent mechanical properties make γ-sialons a promising new class of hard ceramic materials." @default.
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- W2917265566 date "2003-09-26" @default.
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- W2917265566 title "Spinel-SiAlONs— A New Group of Silicon-Based Hard Materials" @default.
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- W2917265566 doi "https://doi.org/10.1002/9783527619924.ch123" @default.
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