Matches in SemOpenAlex for { <https://semopenalex.org/work/W2917414290> ?p ?o ?g. }
- W2917414290 endingPage "266" @default.
- W2917414290 startingPage "240" @default.
- W2917414290 abstract "Abstract This article reviews the most recent advances on the study of non-classical mechanisms for the reduction of organic substrates with hydrosilanes catalyzed by transition metals. A wide variety of catalytic cycles that go beyond the classical steps described for Ojima, Chalk-Harrod and modified Chalk-Harrod mechanisms, as representative examples, have been proposed in recent years. In this review, these alternative mechanistic proposals have been analyzed and classified according to the type of substrate, focusing on the reduction/hydrosilylation of carbonyl compounds (ketones and aldehydes), carbon dioxide, silylesters, amides, N-heterocycles, alkyl halides, nitriles, alkenes and alkynes. In spite of the broad diversity of non-classical reaction mechanisms hitherto reported, the catalytic cycles described for each substrate have been arranged in different categories according to their characteristics. The epigraph dedicated to the first type of substrate (carbonyl compounds) comprises most of the mechanisms described in this review for the reduction of polar bonds, which, to some extent, show a relationship to those proposed for non-polar bonds (alkenes and alkynes). Remarkable types of reaction mechanisms that will be dealt with in this work are: ionic mechanisms, ligand-assisted mechanisms, nonhydride mechanisms, NHC-Cu-H mediated mechanisms, and silylene-mediated mechanisms." @default.
- W2917414290 created "2019-03-02" @default.
- W2917414290 creator A5001744444 @default.
- W2917414290 creator A5002042279 @default.
- W2917414290 creator A5072535084 @default.
- W2917414290 date "2019-05-01" @default.
- W2917414290 modified "2023-10-18" @default.
- W2917414290 title "Non-classical hydrosilane mediated reductions promoted by transition metal complexes" @default.
- W2917414290 cites W1772948919 @default.
- W2917414290 cites W1793500466 @default.
- W2917414290 cites W1949784152 @default.
- W2917414290 cites W1964885234 @default.
- W2917414290 cites W1967715923 @default.
- W2917414290 cites W1968928679 @default.
- W2917414290 cites W1976593663 @default.
- W2917414290 cites W1978566823 @default.
- W2917414290 cites W1979736846 @default.
- W2917414290 cites W1982787432 @default.
- W2917414290 cites W1984724604 @default.
- W2917414290 cites W1985638338 @default.
- W2917414290 cites W1987760965 @default.
- W2917414290 cites W1991971314 @default.
- W2917414290 cites W1992775007 @default.
- W2917414290 cites W1993233047 @default.
- W2917414290 cites W2002933118 @default.
- W2917414290 cites W2003699803 @default.
- W2917414290 cites W2003794153 @default.
- W2917414290 cites W2006153876 @default.
- W2917414290 cites W2007684942 @default.
- W2917414290 cites W2010797442 @default.
- W2917414290 cites W2010877427 @default.
- W2917414290 cites W2011707142 @default.
- W2917414290 cites W2013476776 @default.
- W2917414290 cites W2014284755 @default.
- W2917414290 cites W2022731476 @default.
- W2917414290 cites W2023875511 @default.
- W2917414290 cites W2023933936 @default.
- W2917414290 cites W2027458599 @default.
- W2917414290 cites W2029367096 @default.
- W2917414290 cites W2035816185 @default.
- W2917414290 cites W2038283541 @default.
- W2917414290 cites W2041835823 @default.
- W2917414290 cites W2041885115 @default.
- W2917414290 cites W2042887158 @default.
- W2917414290 cites W2045445198 @default.
- W2917414290 cites W2047393255 @default.
- W2917414290 cites W2048505293 @default.
- W2917414290 cites W2053066220 @default.
- W2917414290 cites W2054009687 @default.
- W2917414290 cites W2055172084 @default.
- W2917414290 cites W2055453175 @default.
- W2917414290 cites W2057033159 @default.
- W2917414290 cites W2057496206 @default.
- W2917414290 cites W2058282121 @default.
- W2917414290 cites W2061297570 @default.
- W2917414290 cites W2061555962 @default.
- W2917414290 cites W2065659172 @default.
- W2917414290 cites W2066747456 @default.
- W2917414290 cites W2068313522 @default.
- W2917414290 cites W2071732510 @default.
- W2917414290 cites W2072254507 @default.
- W2917414290 cites W2072259571 @default.
- W2917414290 cites W2073795257 @default.
- W2917414290 cites W2073865703 @default.
- W2917414290 cites W2074962346 @default.
- W2917414290 cites W2076087133 @default.
- W2917414290 cites W2077980811 @default.
- W2917414290 cites W2080922718 @default.
- W2917414290 cites W2081660555 @default.
- W2917414290 cites W2081732645 @default.
- W2917414290 cites W2083360260 @default.
- W2917414290 cites W2085355013 @default.
- W2917414290 cites W2086780143 @default.
- W2917414290 cites W2088268670 @default.
- W2917414290 cites W2098395204 @default.
- W2917414290 cites W2101687918 @default.
- W2917414290 cites W2104433834 @default.
- W2917414290 cites W2105597435 @default.
- W2917414290 cites W2106898485 @default.
- W2917414290 cites W2115224640 @default.
- W2917414290 cites W2115397911 @default.
- W2917414290 cites W2128842286 @default.
- W2917414290 cites W2133268802 @default.
- W2917414290 cites W2136726885 @default.
- W2917414290 cites W2137820615 @default.
- W2917414290 cites W2140894725 @default.
- W2917414290 cites W2148431077 @default.
- W2917414290 cites W2149361575 @default.
- W2917414290 cites W2159607851 @default.
- W2917414290 cites W2162449746 @default.
- W2917414290 cites W2166921895 @default.
- W2917414290 cites W2169986863 @default.
- W2917414290 cites W2199017923 @default.
- W2917414290 cites W2306861641 @default.
- W2917414290 cites W2311568297 @default.
- W2917414290 cites W2315752527 @default.
- W2917414290 cites W2315869762 @default.
- W2917414290 cites W2316200704 @default.