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- W2917738487 abstract "Incorporating pendant silicon functionalities into phosphine ligands enables to profit from the strong σ‐electron donor and trans influence properties of Si while enhancing the coordination ability of the ligand. Herein, we show that the introduction of bulky sigma donor substituents on the Si atoms and modulation of the number of Si–H functional groups in a series of phosphinobenzylsilanes allow either the stabilization of rare highly unsaturated 14‐electron rhodium(III) and iridium(III) species devoid of agostic interactions or the access to mixed‐valence M I –M III complexes. Our findings using isopropyl‐substituted silicon are markedly different from those obtained when employing the methyl‐substituted Si series." @default.
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- W2917738487 date "2019-03-14" @default.
- W2917738487 modified "2023-10-17" @default.
- W2917738487 title "Exploiting the Versatility of Phosphinobenzylsilanes for the Stabilization of 14‐Electron Rhodium(III) and Iridium(III) Complexes" @default.
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- W2917738487 doi "https://doi.org/10.1002/ejic.201900107" @default.
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