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• W2917966621 abstract "Adipic acid appears as an intermediate compound for the synthesis of polyamides and preferentially for the production of nylon-6,6 polyamide. It can be synthesized by the oxidation of cyclohexene by hydrogen peroxide in microemulsion media which has the main advantage to lead a better contact between the two phases thus increasing the yield of the reaction. The microemulsion is generated by stearyl dimethyl benzyl ammonium chloride (C18) as a surfactant avoiding the use of harmful organic solvents and phase-transfer catalysts. The reaction is performed under mild conditions (85 °C, 8 h) with sodium tungstate, - a no heavy metal catalyst - leading to the production of adipic acid in high yield (>80%). By recycling the catalyst and the surfactant, the process becomes truly green." @default.
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• W2917966621 date "2020-04-01" @default.
• W2917966621 modified "2023-10-18" @default.
• W2917966621 title "Sustainable process for adipic acid production from cyclohexene in microemulsion" @default.
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• W2917966621 doi "https://doi.org/10.1016/j.cattod.2019.02.065" @default.
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