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• W2918253915 abstract "The synthesis and characterization of a chemiluminescent metal-organic framework with high porosity is reported. It consists of Zr6 O6 (OH)4 nodes connected by 4,4'-(anthracene-9,10-diyl)dibenzoate as the linker and luminophore. It shows the topology known for UiO-66 and is therefore denoted PAP-UiO. The MOF was not only obtained as bulk material but also as a thin film. Exposure of PAP-UiO as bulk or film to a mixture of bis-(2,4,6-trichlorophenyl) oxalate, hydrogen peroxide, and sodium salicylate in a mixture of dimethyl and dibutyl phthalate evoked strong and long lasting chemiluminescence of the PAP-UiO crystals. Time dependent fluorescence spectroscopy on bulk PAP-UiO and, for comparison, on dimethyl 4,4'-(anthracene-9,10-diyl)dibenzoate provided evidence that the chemiluminescence originates from luminophores being part of the PAP-UiO, including the luminophores inside the crystals." @default.
• W2918253915 created "2019-03-11" @default.
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• W2918253915 date "2019-04-12" @default.
• W2918253915 modified "2023-10-12" @default.
• W2918253915 title "A Chemiluminescent Metal–Organic Framework" @default.
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• W2918253915 doi "https://doi.org/10.1002/chem.201806041" @default.
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