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• W2918745227 abstract "Sn-based alloy materials are strong candidates to replace graphitic carbon as the anode for the next generation lithium-ion batteries because of their much higher gravimetric and volumetric capacity. A series of nanosize SnyFe alloys derived from the chemical transformation of preformed Sn nanoparticles as templates have been synthesized and characterized. An optimized Sn5Fe/Sn2Fe anode with a core–shell structure delivered 541 mAh·g–1 after 200 cycles at the C/2 rate, retaining close to 100% of the initial capacity. Its volumetric capacity is double that of commercial graphitic carbon. It also has an excellent rate performance, delivering 94.8, 84.3, 72.1, and 58.2% of the 0.1 C capacity (679.8 mAh/g) at 0.2, 0.5, 1 and 2 C, respectively. The capacity is recovered upon lowering the rate. The exceptional cycling/rate capability and higher gravimetric/volumetric capacity make the SnyFe alloy a potential candidate as the anode in lithium-ion batteries. The understanding of SnyFe alloys from this work also provides insight for designing other Sn–M (M = Co, Ni, Cu, Mn, etc.) system." @default.
• W2918745227 created "2019-03-11" @default.
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• W2918745227 date "2019-03-05" @default.
• W2918745227 modified "2023-10-18" @default.
• W2918745227 title "Nanocrystal Conversion-Assisted Design of Sn–Fe Alloy with a Core–Shell Structure as High-Performance Anodes for Lithium-Ion Batteries" @default.
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• W2918745227 doi "https://doi.org/10.1021/acsomega.8b03637" @default.
• W2918745227 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6648940" @default.
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