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- W2919371322 startingPage "3764" @default.
- W2919371322 abstract "Two coordination polymers of the type Co(BPDC)(N-ox), with BPDC being 4,4′-biphenyldicarboxylate and N-ox being pyridine N-oxide (PNO) or isoquinoline N-oxide (IQNO), have been synthesized and characterized. The compounds feature 2D and 3D metal–organic networks that encapsulate Co(II)-based chains in a rigid superstructure. The dc and ac magnetic properties of these Co(BPDC)(N-ox) materials have been investigated alongside those of a related Co(BDC)(PNO) compound (where BDC is 1,4-benzenedicarboxylate), which contains a smaller dicarboxylate linker. These Co(II)-containing coordination polymers exhibit slow magnetic relaxation, as observed by ac susceptibility measurements. The observed magnetic behavior of all compounds is consistent with an antiferromagnetic interaction between canted Co spins along the 1D skeleton, resulting in single-chain magnet behavior. In the case of Co(BPDC)(IQNO), weak interchain magnetic interactions yield 3D antiferromagnetic order while the inherent magnetic behavior stemming from the chain component is maintained. The combination of these effects in this material puts it at the frontier between single-chain magnets and classical bulk antiferromagnets. This work contributes to the limited group of materials featuring the organization of single-chain magnets within a coordination polymer superstructure." @default.
- W2919371322 created "2019-03-11" @default.
- W2919371322 creator A5013131196 @default.
- W2919371322 creator A5021472916 @default.
- W2919371322 creator A5083810662 @default.
- W2919371322 creator A5087052931 @default.
- W2919371322 date "2019-03-05" @default.
- W2919371322 modified "2023-10-05" @default.
- W2919371322 title "Slow Magnetic Relaxation of Co(II) Single Chains Embedded within Metal–Organic Superstructures" @default.
- W2919371322 cites W172207955 @default.
- W2919371322 cites W1963944875 @default.
- W2919371322 cites W1969360633 @default.
- W2919371322 cites W1969885133 @default.
- W2919371322 cites W1970592344 @default.
- W2919371322 cites W1971963959 @default.
- W2919371322 cites W1981783914 @default.
- W2919371322 cites W1993166730 @default.
- W2919371322 cites W1993441703 @default.
- W2919371322 cites W1999758527 @default.
- W2919371322 cites W2002762653 @default.
- W2919371322 cites W2003157597 @default.
- W2919371322 cites W2003819875 @default.
- W2919371322 cites W2006038032 @default.
- W2919371322 cites W2010424953 @default.
- W2919371322 cites W2012419965 @default.
- W2919371322 cites W2018886327 @default.
- W2919371322 cites W2026039351 @default.
- W2919371322 cites W2030304123 @default.
- W2919371322 cites W2032842297 @default.
- W2919371322 cites W2042468198 @default.
- W2919371322 cites W2042549894 @default.
- W2919371322 cites W2046897274 @default.
- W2919371322 cites W2051424909 @default.
- W2919371322 cites W2052989960 @default.
- W2919371322 cites W2056962793 @default.
- W2919371322 cites W2057642180 @default.
- W2919371322 cites W2057874777 @default.
- W2919371322 cites W2057902656 @default.
- W2919371322 cites W2058877933 @default.
- W2919371322 cites W2059205366 @default.
- W2919371322 cites W2059285406 @default.
- W2919371322 cites W2063195695 @default.
- W2919371322 cites W2069828719 @default.
- W2919371322 cites W2070132142 @default.
- W2919371322 cites W2071337849 @default.
- W2919371322 cites W2073506875 @default.
- W2919371322 cites W2073955300 @default.
- W2919371322 cites W2076636805 @default.
- W2919371322 cites W2077422231 @default.
- W2919371322 cites W2080665513 @default.
- W2919371322 cites W2089740902 @default.
- W2919371322 cites W2089796724 @default.
- W2919371322 cites W2092604963 @default.
- W2919371322 cites W2101547779 @default.
- W2919371322 cites W2105485299 @default.
- W2919371322 cites W2106989305 @default.
- W2919371322 cites W2109560330 @default.
- W2919371322 cites W2114373473 @default.
- W2919371322 cites W2119820487 @default.
- W2919371322 cites W2127512223 @default.
- W2919371322 cites W2127544976 @default.
- W2919371322 cites W2128471846 @default.
- W2919371322 cites W2132454074 @default.
- W2919371322 cites W2135374860 @default.
- W2919371322 cites W2135648388 @default.
- W2919371322 cites W2137751968 @default.
- W2919371322 cites W2142431169 @default.
- W2919371322 cites W2146172219 @default.
- W2919371322 cites W2146695448 @default.
- W2919371322 cites W2150545364 @default.
- W2919371322 cites W2151675857 @default.
- W2919371322 cites W2194352041 @default.
- W2919371322 cites W2211195160 @default.
- W2919371322 cites W2234217832 @default.
- W2919371322 cites W2290120852 @default.
- W2919371322 cites W2316819942 @default.
- W2919371322 cites W2316911401 @default.
- W2919371322 cites W2317598425 @default.
- W2919371322 cites W2318044185 @default.
- W2919371322 cites W2318049588 @default.
- W2919371322 cites W2320297017 @default.
- W2919371322 cites W2321320462 @default.
- W2919371322 cites W2323637590 @default.
- W2919371322 cites W2324766838 @default.
- W2919371322 cites W2326031882 @default.
- W2919371322 cites W2330535805 @default.
- W2919371322 cites W2330652590 @default.
- W2919371322 cites W2330895604 @default.
- W2919371322 cites W2332402427 @default.
- W2919371322 cites W2332849404 @default.
- W2919371322 cites W2395571735 @default.
- W2919371322 cites W2408899784 @default.
- W2919371322 cites W2412401467 @default.
- W2919371322 cites W2421689020 @default.
- W2919371322 cites W2470375687 @default.
- W2919371322 cites W2518153592 @default.
- W2919371322 cites W2556743604 @default.
- W2919371322 cites W2567547933 @default.