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- W2919875835 abstract ": Calix[4]monoquinone (3) has been synthesized by oxidation of rigid cone conformation of tripropoxy calix[4]arene (2), and conformational characteristics of this molecule have been studied by means of dynamic nuclear magnetic resonance (DNMR) and HH- correlated nuclear magnetic resonance spectroscopy (HH-COSY NMR). On the basis of the data that have been obtained, free Gibbs energy of activation (ΔG#) for quinone ring interconversion process of 3 was determined 12.3±0.05 Kcal/mol by coalescence approximation method." @default.
- W2919875835 created "2019-03-11" @default.
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- W2919875835 date "2020-01-07" @default.
- W2919875835 modified "2023-09-24" @default.
- W2919875835 title "Conformational Mobility Study in Mono Quinone Derivative of Calix[4]arene by Low Temperature NMR Spectroscopy" @default.
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- W2919875835 doi "https://doi.org/10.2174/1570178616666190228130119" @default.
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