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• W2920046770 abstract "The cross second virial coefficients and dilute gas shear viscosities, thermal conductivities, and binary diffusion coefficients of the systems (CH4 + C2H6) and (N2 + C2H6) were determined at temperatures from 90 K to 1200 K using statistical thermodynamics and the kinetic theory of molecular gases. The required intermolecular potential energy surfaces (PESs) for CH4–C2H6 and N2–C2H6 interactions are presented in this work, while the like-species interactions were modeled using PESs from our previous studies on the pure gases. All of these PESs are based on high-level quantum-chemical ab initio calculations and were fine-tuned to the most accurate experimental data available for the second virial and cross second virial coefficients. The agreement of the calculated values for all investigated thermophysical properties with the best experimental data is overall very satisfactory and confirms the high accuracy of the calculated values." @default.
• W2920046770 created "2019-03-11" @default.
• W2920046770 creator A5020523237 @default.
• W2920046770 date "2019-07-01" @default.
• W2920046770 modified "2023-09-27" @default.
• W2920046770 title "Cross second virial coefficients and dilute gas transport properties of the systems (CH4 + C2H6) and (N2 + C2H6) from accurate intermolecular potential energy surfaces" @default.
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• W2920046770 doi "https://doi.org/10.1016/j.jct.2019.03.002" @default.
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