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- W2920513761 abstract "Two multifunctional lanthanide complexes, namely [Dy(HL)]·CH3OH (1) and [Er(HL)]·CH3OH (2), [H4L = N,N′,N′′,N′′′-tetra(3,5-dimethyl-2-Hydroxybenzyl)-1,4,7,10-tetraazacyclododecane] were synthesized and structurally characterized. Complexes 1 and 2 are isomorphic and crystallize in the non-centrosymmetric orthorhombic space group Pca21. Their structure consists of one seven-coordinated LnIII ion with the coordination geometry of trigonal prism, one HL3– ligand and one lattice methanol molecule. They exhibit second-harmonic generation (SHG) effect. Complex 1 displays strong fluorescent emissions, which are typical narrow emission bands of lanthanide ions. In addition, complex 1 features field-induced slow magnetic relaxation behavior. Therefore, complex 1 may be a potential multifunctional molecular material." @default.
- W2920513761 created "2019-03-11" @default.
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- W2920513761 date "2019-03-01" @default.
- W2920513761 modified "2023-10-10" @default.
- W2920513761 title "Multifunctional Lanthanide Complexes Based on Tetraazacyclolamidophenol Ligand with Field‐Induced Slow Magnetic Relaxation, Luminescent and SHG Properties" @default.
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- W2920513761 doi "https://doi.org/10.1002/ejic.201801492" @default.
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