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- W2920697239 abstract "Abstract Two unique isostructural anion channel-type metal-organnic frameworks (MOFs), with molecular formula {[Et2NH2][M1.5(Ina)(HIna)(μ2-OH)(TPTC)0.5]}n (M = Co - SXNU-J1, Ni - SXNU-J2, SXNU = Shanxi Normal University) were synthesized under solvothermal conditions using M(Ac)2·4H2O and mixed ligands of H4TPTC (p - terphenyl - 3, 3″, 5, 5‴ - tetracaboxylic acid) and (HIna) isonicotinic acid. The as-synthesized two MOFs display blue luminescence and are further proven to a promising luminescence sensor for selective and sensitive detection of Fe3+. Especially, the SXNU-J1 and SXNU-J2 exhibit extra sensitivity (Ksv (SXNU-J1) = 4069.3 M−1 and Ksv (SXNU-J2) = 5262.8 M−1) and high sensitivity of Fe3+ (LOD(SXNU-J1) = 0.003391 mM and LOD(SXNU-J2) = 0.003677 mM). This two 3D isostructural high (4, 8)-connected topological MOFs are a potential candidate that can be developed into a highly selective and sensitive device for the in-field detection of Fe3+." @default.
- W2920697239 created "2019-03-11" @default.
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- W2920697239 date "2019-06-01" @default.
- W2920697239 modified "2023-10-15" @default.
- W2920697239 title "Decoration of bare carboxyl group on the pore surface of metal-organic frameworks for high selective fluorescence Fe3+ detection" @default.
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- W2920697239 doi "https://doi.org/10.1016/j.jssc.2019.02.035" @default.
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