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• W2920787440 endingPage "1680" @default.
• W2920787440 startingPage "1676" @default.
• W2920787440 abstract "In this paper, selective cleavage and tunable functionalization of the inert C–C/C–N bonds in N-arylpiperidines promoted by tBuONO under metal-free conditions is presented. To be specific, when the reaction was run in acetonitrile in the presence of molecular sieves, the synthetically useful acyclic N-formyl nitriles are formed. On the other hand, when alcohol was used as the reaction medium, the corresponding reactions afforded N-nitroso chain esters as dominating products via a mechanistically different pathway." @default.
• W2920787440 created "2019-03-11" @default.
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• W2920787440 date "2019-03-04" @default.
• W2920787440 modified "2023-10-17" @default.
• W2920787440 title "Selective Cleavage and Tunable Functionalization of the C–C/C–N Bonds of <i>N</i>-Arylpiperidines Promoted by ^<i>t</i>BuONO" @default.
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• W2920787440 doi "https://doi.org/10.1021/acs.orglett.9b00226" @default.
• W2920787440 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30829493" @default.
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