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• W2920805938 endingPage "3724" @default.
• W2920805938 startingPage "3716" @default.
• W2920805938 abstract "The oxidative activation of alkyl C–H bonds vs arene C–H bonds with Pd(OAc)2 has been found to be generalizable to a number of nucleophilic substrates, allowing the formation of a range of hindered quaternary centers. The substrates share a common mechanistic path wherein Pd(II) initiates an oxidative dimerization. The resultant dimer modifies the palladium catalyst to favor activation of alkyl C–H bonds, in contrast to the trends typically observed via a concerted metalation–deprotonation mechanism. Notably, insertion occurs at the terminus of the alkyl arene for hindered substrates. Two different oxidant systems were discovered that turn over the process. Parameters have been identified that predict which substrates are productive in this reaction." @default.
• W2920805938 created "2019-03-22" @default.
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• W2920805938 date "2019-03-08" @default.
• W2920805938 modified "2023-10-14" @default.
• W2920805938 title "Palladium-Catalyzed Chemoselective Activation of sp³ vs sp² C–H Bonds: Oxidative Coupling To Form Quaternary Centers" @default.
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• W2920805938 doi "https://doi.org/10.1021/acscatal.9b00091" @default.
• W2920805938 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6880961" @default.
• W2920805938 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31777683" @default.
• W2920805938 hasPublicationYear "2019" @default.
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