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- W2920806746 abstract "Abstract We report the high‐pressure structural characterization of an organic polyiodide salt in which a progressive addition of iodine to triiodide groups occurs. Compression leads to the initial formation of discrete heptaiodide units, followed by polymerization to a 3D anionic network. Although the structural changes appear to be continuous, the insulating salt becomes a semiconducting polymer above 10 GPa. The features of the pre‐reactive state and the polymerized state are revealed by analysis of the computed electron and energy densities. The unusually high electrical conductivity can be explained with the formation of new bonds." @default.
- W2920806746 created "2019-03-22" @default.
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- W2920806746 date "2019-04-08" @default.
- W2920806746 modified "2023-10-18" @default.
- W2920806746 title "Pressure‐Induced Polymerization and Electrical Conductivity of a Polyiodide" @default.
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- W2920806746 doi "https://doi.org/10.1002/anie.201901178" @default.
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