Matches in SemOpenAlex for { <https://semopenalex.org/work/W2920808420> ?p ?o ?g. }
- W2920808420 endingPage "1900153" @default.
- W2920808420 startingPage "1900153" @default.
- W2920808420 abstract "Boron-doped diamond-based electrochemical advanced oxidation processes (BDD-EAOPs) have attracted much attention. However, few systematic studies concerning the radical mechanism in BDD-EAOPs have been published. In situ electron paramagnetic resonance spectrometry is used to confirm that SO4•- is directly electrogenerated from SO42- . Then, excess SO4•- dimerizes to form S2 O82- and accumulates in the BDD-EAOP system. But no S2 O82- accumulates at pH = 10 owing to the rapid transformation of SO4•- and S2 O82- . Above the overpotential of water oxidation, • OH is electrogenerated and cooperated with SO4•- . In the power-off phase, the accumulated S2 O82- can be reactivated to SO4•- via specific degradation intermediates to achieve sustainable degradation. Di-n-butyl phthalate (DnBP), a typical endocrine disruptor, is selected as a model contaminant. Surprisingly, 99.8% of DnBP (initial concentration of 1 mg L-1 ) is removed, using an intermittent power supply strategy with a periodic 10 min power-on phase at a duty ratio of 1:2, reducing the electrical energy consumption (1.8 kWh m-3 ) by more than 30% compared with continuous power supply consumption. These radical electrogeneration transformation mechanisms reveal an important new strategy for sustainable oxidation, especially for in situ water restoration, and are expected to provide a theoretical basis for BDD applications." @default.
- W2920808420 created "2019-03-22" @default.
- W2920808420 creator A5025679709 @default.
- W2920808420 creator A5031246510 @default.
- W2920808420 creator A5059651600 @default.
- W2920808420 creator A5071668194 @default.
- W2920808420 date "2019-03-08" @default.
- W2920808420 modified "2023-10-08" @default.
- W2920808420 title "Boron‐Doped Diamond for Hydroxyl Radical and Sulfate Radical Anion Electrogeneration, Transformation, and Voltage‐Free Sustainable Oxidation" @default.
- W2920808420 cites W1128106189 @default.
- W2920808420 cites W1964675752 @default.
- W2920808420 cites W1967211742 @default.
- W2920808420 cites W1981207990 @default.
- W2920808420 cites W1982580600 @default.
- W2920808420 cites W1984045894 @default.
- W2920808420 cites W2001700734 @default.
- W2920808420 cites W2005774635 @default.
- W2920808420 cites W2009934678 @default.
- W2920808420 cites W2012452880 @default.
- W2920808420 cites W2016439750 @default.
- W2920808420 cites W2040667521 @default.
- W2920808420 cites W2051743392 @default.
- W2920808420 cites W2065881882 @default.
- W2920808420 cites W2072187875 @default.
- W2920808420 cites W2076288335 @default.
- W2920808420 cites W2090963895 @default.
- W2920808420 cites W2096235342 @default.
- W2920808420 cites W2166139511 @default.
- W2920808420 cites W2171083338 @default.
- W2920808420 cites W2183984674 @default.
- W2920808420 cites W2255675712 @default.
- W2920808420 cites W2277696037 @default.
- W2920808420 cites W2290180541 @default.
- W2920808420 cites W2298431938 @default.
- W2920808420 cites W2298551106 @default.
- W2920808420 cites W2321363019 @default.
- W2920808420 cites W2343782327 @default.
- W2920808420 cites W2466392931 @default.
- W2920808420 cites W2508930034 @default.
- W2920808420 cites W2559414035 @default.
- W2920808420 cites W2565550374 @default.
- W2920808420 cites W2596635308 @default.
- W2920808420 cites W2602624790 @default.
- W2920808420 cites W2617656420 @default.
- W2920808420 cites W2761051420 @default.
- W2920808420 cites W2763391259 @default.
- W2920808420 cites W2765726697 @default.
- W2920808420 cites W2774552145 @default.
- W2920808420 cites W2791451920 @default.
- W2920808420 cites W2792106404 @default.
- W2920808420 cites W2794463075 @default.
- W2920808420 cites W2795788542 @default.
- W2920808420 cites W2798207716 @default.
- W2920808420 cites W2800558735 @default.
- W2920808420 cites W2800640896 @default.
- W2920808420 cites W2801544527 @default.
- W2920808420 cites W2802574737 @default.
- W2920808420 cites W2883062373 @default.
- W2920808420 cites W2887285882 @default.
- W2920808420 cites W2900533925 @default.
- W2920808420 cites W2901801421 @default.
- W2920808420 cites W2949633926 @default.
- W2920808420 doi "https://doi.org/10.1002/smll.201900153" @default.
- W2920808420 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30848873" @default.
- W2920808420 hasPublicationYear "2019" @default.
- W2920808420 type Work @default.
- W2920808420 sameAs 2920808420 @default.
- W2920808420 citedByCount "41" @default.
- W2920808420 countsByYear W29208084202019 @default.
- W2920808420 countsByYear W29208084202020 @default.
- W2920808420 countsByYear W29208084202021 @default.
- W2920808420 countsByYear W29208084202022 @default.
- W2920808420 countsByYear W29208084202023 @default.
- W2920808420 crossrefType "journal-article" @default.
- W2920808420 hasAuthorship W2920808420A5025679709 @default.
- W2920808420 hasAuthorship W2920808420A5031246510 @default.
- W2920808420 hasAuthorship W2920808420A5059651600 @default.
- W2920808420 hasAuthorship W2920808420A5071668194 @default.
- W2920808420 hasConcept C121332964 @default.
- W2920808420 hasConcept C127413603 @default.
- W2920808420 hasConcept C139066938 @default.
- W2920808420 hasConcept C145148216 @default.
- W2920808420 hasConcept C147789679 @default.
- W2920808420 hasConcept C17525397 @default.
- W2920808420 hasConcept C178790620 @default.
- W2920808420 hasConcept C185592680 @default.
- W2920808420 hasConcept C186460083 @default.
- W2920808420 hasConcept C187961010 @default.
- W2920808420 hasConcept C192562407 @default.
- W2920808420 hasConcept C2776921476 @default.
- W2920808420 hasConcept C2779679103 @default.
- W2920808420 hasConcept C41008148 @default.
- W2920808420 hasConcept C42360764 @default.
- W2920808420 hasConcept C46141821 @default.
- W2920808420 hasConcept C501308230 @default.
- W2920808420 hasConcept C52859227 @default.
- W2920808420 hasConcept C68801617 @default.
- W2920808420 hasConcept C76155785 @default.