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- W2920967138 abstract "Four conformers of the n-propyl-substituted Criegee intermediate, CH3CH2CH2CHOO, also named n-butyraldehyde oxide, have been observed by Fourier transform microwave spectroscopy. The transient species was produced using a pulsed electric discharge of a gas mixture of 1,1-diiodobutane/O2 diluted in Ar or Ne. The observation of only syn species is in contrast to the results of other previous studies of alkyl-substituted Criegee intermediates, in particular, those for the structural isomers, isobutyraldehyde oxide ((CH3)2CHCHOO), and methyl-ethyl-ketone oxide (C2H5C(CH3)OO), for which syn and anti species have been observed coexisting in the gas phase." @default.
- W2920967138 created "2019-03-22" @default.
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- W2920967138 date "2019-03-14" @default.
- W2920967138 modified "2023-10-16" @default.
- W2920967138 title "Fourier transform microwave spectroscopy of Criegee intermediates: The conformational behaviour of butyraldehyde oxide" @default.
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- W2920967138 doi "https://doi.org/10.1063/1.5088566" @default.
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