Matches in SemOpenAlex for { <https://semopenalex.org/work/W2921217071> ?p ?o ?g. }
- W2921217071 endingPage "167" @default.
- W2921217071 startingPage "157" @default.
- W2921217071 abstract "The sorption of N2, Ar, and CO2 in the glassy polymer with intrinsic microporosity PIM-1 has been investigated across a broad temperature range, from cryogenic (77 K) to near room temperature (275 K). The data obtained have been interpreted by the non-equilibrium thermodynamic model for glassy polymers (NET-GP), which accurately describes the experimental behaviors, and is used to predict the solubility of the same gases above room temperature. The analysis reveals that the same mechanism drives the sorption process over the broad temperature range inspected, with physical dissolution of the gas in the glassy matrix accompanied by significant swelling of the polymer occurring largely in the central portion of the isotherm at cryogenic temperatures. These findings clearly support the idea that calculation of the BET surface area for amorphous high free-volume glassy polymers does not represent an actual real physical property and suggest that its value is an unsuitable metric of polymer material properties. The gas uptake obtained in the cryogenic sorption isotherm is clearly related to the excess free volume and may instead serve as a more appropriate metric for comparison between different polymers." @default.
- W2921217071 created "2019-03-22" @default.
- W2921217071 creator A5021581245 @default.
- W2921217071 creator A5024234024 @default.
- W2921217071 creator A5058488243 @default.
- W2921217071 creator A5077299953 @default.
- W2921217071 creator A5081117767 @default.
- W2921217071 date "2019-04-01" @default.
- W2921217071 modified "2023-10-16" @default.
- W2921217071 title "Analysis and utilization of cryogenic sorption isotherms for high free volume glassy polymers" @default.
- W2921217071 cites W1744421352 @default.
- W2921217071 cites W1967242764 @default.
- W2921217071 cites W1971066254 @default.
- W2921217071 cites W1974743214 @default.
- W2921217071 cites W1985639321 @default.
- W2921217071 cites W1986446261 @default.
- W2921217071 cites W1988454652 @default.
- W2921217071 cites W1988711878 @default.
- W2921217071 cites W1992541116 @default.
- W2921217071 cites W1993365709 @default.
- W2921217071 cites W1993842572 @default.
- W2921217071 cites W2004645560 @default.
- W2921217071 cites W2007165520 @default.
- W2921217071 cites W2009061103 @default.
- W2921217071 cites W2009200509 @default.
- W2921217071 cites W2010144656 @default.
- W2921217071 cites W2011254969 @default.
- W2921217071 cites W2015458600 @default.
- W2921217071 cites W2018899624 @default.
- W2921217071 cites W2020505679 @default.
- W2921217071 cites W2022353023 @default.
- W2921217071 cites W2023911289 @default.
- W2921217071 cites W2026098623 @default.
- W2921217071 cites W2036366605 @default.
- W2921217071 cites W2042272880 @default.
- W2921217071 cites W2042349865 @default.
- W2921217071 cites W2047404361 @default.
- W2921217071 cites W2050343674 @default.
- W2921217071 cites W2053797945 @default.
- W2921217071 cites W2056603291 @default.
- W2921217071 cites W2056977789 @default.
- W2921217071 cites W2068276685 @default.
- W2921217071 cites W2076662543 @default.
- W2921217071 cites W2084284690 @default.
- W2921217071 cites W2084754526 @default.
- W2921217071 cites W2085237940 @default.
- W2921217071 cites W2086010624 @default.
- W2921217071 cites W2087470081 @default.
- W2921217071 cites W2094592409 @default.
- W2921217071 cites W2105898331 @default.
- W2921217071 cites W2116414302 @default.
- W2921217071 cites W2129222518 @default.
- W2921217071 cites W2131085950 @default.
- W2921217071 cites W2151030852 @default.
- W2921217071 cites W2152214358 @default.
- W2921217071 cites W2158584131 @default.
- W2921217071 cites W2165712856 @default.
- W2921217071 cites W2165931929 @default.
- W2921217071 cites W2171558687 @default.
- W2921217071 cites W2215509697 @default.
- W2921217071 cites W2313539070 @default.
- W2921217071 cites W2319784388 @default.
- W2921217071 cites W2323807389 @default.
- W2921217071 cites W2333150167 @default.
- W2921217071 cites W2339440141 @default.
- W2921217071 cites W2508710665 @default.
- W2921217071 cites W2515673718 @default.
- W2921217071 cites W2549977163 @default.
- W2921217071 cites W2587924017 @default.
- W2921217071 cites W2593940448 @default.
- W2921217071 cites W2667550546 @default.
- W2921217071 cites W2734575657 @default.
- W2921217071 cites W2739875301 @default.
- W2921217071 cites W2747401919 @default.
- W2921217071 cites W2767597022 @default.
- W2921217071 cites W2789706604 @default.
- W2921217071 cites W2802587233 @default.
- W2921217071 cites W2885523385 @default.
- W2921217071 cites W2904988045 @default.
- W2921217071 cites W4242552083 @default.
- W2921217071 cites W608800932 @default.
- W2921217071 doi "https://doi.org/10.1016/j.polymer.2019.03.012" @default.
- W2921217071 hasPublicationYear "2019" @default.
- W2921217071 type Work @default.
- W2921217071 sameAs 2921217071 @default.
- W2921217071 citedByCount "12" @default.
- W2921217071 countsByYear W29212170712019 @default.
- W2921217071 countsByYear W29212170712020 @default.
- W2921217071 countsByYear W29212170712021 @default.
- W2921217071 countsByYear W29212170712022 @default.
- W2921217071 countsByYear W29212170712023 @default.
- W2921217071 crossrefType "journal-article" @default.
- W2921217071 hasAuthorship W2921217071A5021581245 @default.
- W2921217071 hasAuthorship W2921217071A5024234024 @default.
- W2921217071 hasAuthorship W2921217071A5058488243 @default.
- W2921217071 hasAuthorship W2921217071A5077299953 @default.
- W2921217071 hasAuthorship W2921217071A5081117767 @default.
- W2921217071 hasConcept C121332964 @default.