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• W2921270598 abstract "Tunable blue-green-yellow emitting Sr3YNa(PO4)3F (SYNPF):Ce3+,Tb3+,Mn2+ phosphors have been prepared via a high-temperature solid-state reaction method. The structural and luminescent properties, energy transfer (ET) mechanism, and thermal quenching of the samples are investigated in detail. The ET from Ce3+ to Tb3+ and Mn2+ in SYNPF is identified as the interaction of the electric dipole-quadrupole with ET efficiencies of 81.6% and 69.3%, respectively. The critical distances for Ce3+/Tb3+ and Ce3+/Mn2+ are calculated through the spectral overlap method to be 9.54 and 10.92 Å. Under UV excitation, high-efficiency tunable blue-green-yellow emissions from Ce3+ to Tb3+ and Mn2+ can be obtained. Moreover, white light can also be achieved by adjusting the stoichiometry of Ce3+ and Mn2+ properly in the SYNPF phosphor. In addition, the temperature-dependent luminescence spectra exhibit good thermal quenching behaviors for the as-prepared phosphors. The above results suggest that SYNPF:Ce3+,Tb3+,Mn2+ phosphors can act as color-tunable emission phosphors for potential applications in WLEDs." @default.
• W2921270598 created "2019-03-22" @default.
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• W2921270598 date "2019-03-12" @default.
• W2921270598 modified "2023-10-16" @default.
• W2921270598 title "Blue–Green–Yellow Color-Tunable Luminescence of Ce³⁺-, Tb³⁺-, and Mn²⁺-Codoped Sr₃YNa(PO₄)₃F via Efficient Energy Transfer" @default.
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• W2921270598 doi "https://doi.org/10.1021/acs.inorgchem.9b00030" @default.
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• W2921270598 hasPublicationYear "2019" @default.
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