Matches in SemOpenAlex for { <https://semopenalex.org/work/W2921388458> ?p ?o ?g. }
- W2921388458 endingPage "4539" @default.
- W2921388458 startingPage "4534" @default.
- W2921388458 abstract "We report a hierarchical self-assembly engineering of tin–oxo clusters from nanosized hydrophobic clusters to a single-layer film of assembled clusters. These clusters are derivatives of the previously reported Na-centered butyltin Keggin ions, but they are bicapped with butyltin and with borate ligands. The formulas γ-[(n-BuSn)14(OCH3)10(OH)3O9(NaO4)(HBO3)2] and γ-[(n-BuSn)14(OCH3)10(OH)3O9(NaO4)(PhBO2)2] were determined from single-crystal X-ray diffraction and bulk solution characterization including small-angle X-ray scattering, electrospray ionization mass spectrometry, and multinuclear and multidimensional NMR (119Sn, 13C, and 1H). Solution characterization confirms that borate functionalization inhibits the solution-phase β–γ Keggin isomer interconversion that was recognized prior for uncapped butyltin clusters, and in this case, the γ isomer is favored. The assembly of the γ-NaSn14BO3 clusters into a homogeneous Langmuir–Blodgett monolayer is the first step toward creating nanopatterned films for microelectronic devices." @default.
- W2921388458 created "2019-03-22" @default.
- W2921388458 creator A5026399447 @default.
- W2921388458 creator A5038465531 @default.
- W2921388458 creator A5043766645 @default.
- W2921388458 creator A5056262061 @default.
- W2921388458 creator A5057209439 @default.
- W2921388458 date "2019-03-18" @default.
- W2921388458 modified "2023-10-14" @default.
- W2921388458 title "Stabilizing γ-Alkyltin–Oxo Keggin Ions by Borate Functionalization" @default.
- W2921388458 cites W1972708655 @default.
- W2921388458 cites W1995916393 @default.
- W2921388458 cites W1998816219 @default.
- W2921388458 cites W2001970457 @default.
- W2921388458 cites W2004138201 @default.
- W2921388458 cites W2015288243 @default.
- W2921388458 cites W2016708947 @default.
- W2921388458 cites W2032189785 @default.
- W2921388458 cites W2035127456 @default.
- W2921388458 cites W2048747442 @default.
- W2921388458 cites W2066904165 @default.
- W2921388458 cites W2070513962 @default.
- W2921388458 cites W2078662446 @default.
- W2921388458 cites W2091852645 @default.
- W2921388458 cites W2092467983 @default.
- W2921388458 cites W2093182063 @default.
- W2921388458 cites W2126733471 @default.
- W2921388458 cites W2128172145 @default.
- W2921388458 cites W2143480266 @default.
- W2921388458 cites W2154838762 @default.
- W2921388458 cites W2160479122 @default.
- W2921388458 cites W2295691216 @default.
- W2921388458 cites W2525093705 @default.
- W2921388458 cites W2558338799 @default.
- W2921388458 cites W2588735259 @default.
- W2921388458 cites W2622137643 @default.
- W2921388458 cites W2623465277 @default.
- W2921388458 cites W2737523853 @default.
- W2921388458 cites W2795381758 @default.
- W2921388458 cites W2807683730 @default.
- W2921388458 cites W2810275072 @default.
- W2921388458 cites W2894040743 @default.
- W2921388458 cites W3165116524 @default.
- W2921388458 cites W4231341983 @default.
- W2921388458 doi "https://doi.org/10.1021/acs.inorgchem.9b00093" @default.
- W2921388458 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30883101" @default.
- W2921388458 hasPublicationYear "2019" @default.
- W2921388458 type Work @default.
- W2921388458 sameAs 2921388458 @default.
- W2921388458 citedByCount "15" @default.
- W2921388458 countsByYear W29213884582019 @default.
- W2921388458 countsByYear W29213884582020 @default.
- W2921388458 countsByYear W29213884582021 @default.
- W2921388458 countsByYear W29213884582022 @default.
- W2921388458 crossrefType "journal-article" @default.
- W2921388458 hasAuthorship W2921388458A5026399447 @default.
- W2921388458 hasAuthorship W2921388458A5038465531 @default.
- W2921388458 hasAuthorship W2921388458A5043766645 @default.
- W2921388458 hasAuthorship W2921388458A5056262061 @default.
- W2921388458 hasAuthorship W2921388458A5057209439 @default.
- W2921388458 hasConcept C115537861 @default.
- W2921388458 hasConcept C145148216 @default.
- W2921388458 hasConcept C147789679 @default.
- W2921388458 hasConcept C161790260 @default.
- W2921388458 hasConcept C162356407 @default.
- W2921388458 hasConcept C178790620 @default.
- W2921388458 hasConcept C185592680 @default.
- W2921388458 hasConcept C26856880 @default.
- W2921388458 hasConcept C2777498215 @default.
- W2921388458 hasConcept C40684141 @default.
- W2921388458 hasConcept C43617362 @default.
- W2921388458 hasConcept C501308230 @default.
- W2921388458 hasConcept C525849907 @default.
- W2921388458 hasConcept C55493867 @default.
- W2921388458 hasConcept C7070889 @default.
- W2921388458 hasConcept C8010536 @default.
- W2921388458 hasConceptScore W2921388458C115537861 @default.
- W2921388458 hasConceptScore W2921388458C145148216 @default.
- W2921388458 hasConceptScore W2921388458C147789679 @default.
- W2921388458 hasConceptScore W2921388458C161790260 @default.
- W2921388458 hasConceptScore W2921388458C162356407 @default.
- W2921388458 hasConceptScore W2921388458C178790620 @default.
- W2921388458 hasConceptScore W2921388458C185592680 @default.
- W2921388458 hasConceptScore W2921388458C26856880 @default.
- W2921388458 hasConceptScore W2921388458C2777498215 @default.
- W2921388458 hasConceptScore W2921388458C40684141 @default.
- W2921388458 hasConceptScore W2921388458C43617362 @default.
- W2921388458 hasConceptScore W2921388458C501308230 @default.
- W2921388458 hasConceptScore W2921388458C525849907 @default.
- W2921388458 hasConceptScore W2921388458C55493867 @default.
- W2921388458 hasConceptScore W2921388458C7070889 @default.
- W2921388458 hasConceptScore W2921388458C8010536 @default.
- W2921388458 hasFunder F4320306203 @default.
- W2921388458 hasFunder F4320321001 @default.
- W2921388458 hasFunder F4320321878 @default.
- W2921388458 hasFunder F4320332161 @default.
- W2921388458 hasFunder F4320332179 @default.
- W2921388458 hasIssue "7" @default.