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- W2921801589 abstract "Self-assembled two-dimensional lead-free inorganic-organic hybrids, (C12H25NH3)2Cu(Cl1-xBrx)4 and (C6H9C2H4NH3)2Cu(Cl1-xBrx)4 have been investigated for various compositions 0 ≤ x ≤ 1. Uniformly crystalline single phase (C12H25NH3)2Cu(Cl1-xBrx)4 systems are grown layer by layer along the c-axis. In the case of (C6H9C2H4NH3)2Cu(Cl1-xBrx)4, we find binary crystalline phase for the composition 0 < x ≤ 1 and structural frustration is indicated through the observation of split in the (00l) diffraction peaks. For both the systems, Raman vibrational modes in the range of 70–400 cm−1 are related to buckling of distorted octahedra of CuX6 (X = Cl and Br) in the inorganic planes. The Raman frequencies compositional red-shift is due to the reduced bonding strength of the Cu-X vibrations by the replacement of higher electronegative Cl atoms with lower electronegative Br atoms. In the infrared spectrum also, symmetric (∼1491 cm−1) and asymmetric (∼1582 cm−1) deformations of NH3-X bonds show a redshift in the frequency with the increasing Br-content in both types of systems. The optical absorption spectra, typical d-d transitions in Cu2+ and consistent band-edge related redshift features have been discussed in detail." @default.
- W2921801589 created "2019-03-22" @default.
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- W2921801589 date "2019-05-01" @default.
- W2921801589 modified "2023-10-01" @default.
- W2921801589 title "Structural and optical diversity in copper halide-based ferromagnetic inorganic-organic layered hybrids" @default.
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- W2921801589 doi "https://doi.org/10.1016/j.jssc.2019.03.012" @default.
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